Bulletin of the Korean Chemical Society

  • 제32권5호
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  • Pages.1543-1546
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Selective Monobromination of 1,3-Diones with N-Bromosaccharin/Mg(ClO4)2 System in Solution and under Solvent-Free Conditions

  • 투고 : 2011.02.28
  • 심사 : 2011.03.18
  • 발행 : 2011.05.20
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초록

N-Bromosaccharin/$Mg(ClO_4)_2$ is an effective and regioselective system for ${\alpha}$-monobromination of 1,3-dicarbonyl compounds. A wide variety of ${\beta}$-keto esters and 1,3-diketones in reaction with this system afforded a regioselectively ${\alpha}$-monobrominated products. The bromination reaction can be conducted at 0-5 $^{\circ}C$ either in solution or under solvent-free conditions.

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피인용 문헌

  1. ChemInform Abstract: Selective Monobromination of 1,3-Diones with N-Bromosaccharin/Mg(ClO4)2 System in Solution and under Solvent-Free Conditions. vol.42, pp.43, 2011, https://doi.org/10.1002/chin.201143037
  2. An Efficient Method for Multicomponent Synthesis of Spiro[4H-pyran-oxindole] Derivatives Catalyzed by Magnesium Perchlorate vol.34, pp.8, 2013, https://doi.org/10.5012/bkcs.2013.34.8.2431
  3. Use of Bromine and Bromo-Organic Compounds in Organic Synthesis vol.116, pp.12, 2016, https://doi.org/10.1021/acs.chemrev.5b00400
  4. An Efficient Synthesis of Spiro[indoline-3,9′-xanthene]trione Derivatives Catalyzed by Magnesium Perchlorate vol.22, pp.8, 2017, https://doi.org/10.3390/molecules22081295
  5. Structures in solid state and solution of dimethoxy curcuminoids: regioselective bromination and chlorination vol.7, pp.None, 2011, https://doi.org/10.1186/1752-153x-7-107
  6. Trihaloisocyanuric Acids as Atom‐Economic Reagents for Halogenation of Aromatics and Carbonyl Compounds in the Solid State by Ball Milling vol.2015, pp.12, 2015, https://doi.org/10.1002/ejoc.201403463
  7. Artificial sugar saccharin and its derivatives: role as a catalyst vol.10, pp.60, 2011, https://doi.org/10.1039/d0ra05974a