Poly(ethylene Terephthalate) 필름의 표면 모폴로지가 고형오구의 세척성에 미치는 영향 (III)

The Effects of Poly(ethylene terephthalate) Film Surface Morphology on Particulate Soil Detergency (III)

  • 강인숙 (창원대학교 자연과학대학 의류학과)
  • Kang, In-Sook (Department of Clothing & Textiles, Changwon National University)
  • 투고 : 2011.10.07
  • 심사 : 2011.12.08
  • 발행 : 2011.12.31

초록

The effect of surface morphology of poly(ethylene terephthalate) (PET) film on the detergency of particulate soil was investigated as functions of surfactant concentration, ionic strength, electrolytes type, washing time and particle size. The PET surface film was modified with NaOH and dimethylformamide (DMF) for different times. Generally, the removal of particles from the PET film treated with NaOH and DMF was relatively higher than that of nontreated film in both nonyl-phenol polyoxyethylene ether and sodium dodecyl-benzene sulfonate solution. The removal of particles from the film increased with increasing concentration of surfactant and ionic strength regardless of treated condition, but the effects of electrolytes type, washing time and particle size on the removal of particle from the PET film varied with treated condition such as chemical type (NaOH or DMF) and treatment time. The removal of ${\alpha}-Fe_2O_3$ particles from the PET film treated with NaOH and DMF were better related with surface energies than surface roughness and surface area. The correlation coefficient between the removal of particle from the film and adsorption of surfactants to film was 0.9.

키워드

과제정보

연구 과제 주관 기관 : 한국학술진흥재단

참고문헌

  1. D. J. Shaw, "Introduction to Colloid and Surface Chemistry", Butter-Worths, London, 1970, pp.161-183.
  2. T. Imamura and F. Tokiwa, "The Comparison of Interfacial Electrical Effects on the Detergency Calculated from the DLVO Theory with Those from Hetero Coagulation Theory", Nippon Kagaku Kaishi, 1976, 6, 869-881.
  3. D. V. Robert and J. V. Marjorie, "Colloid Interface Chemistry", Addison-Wesley, London, 1983, pp.164-167.
  4. I. Krznaric and N. Kally, "Stability of Ag/I Colloid in the Presence of Ionic Surface Active Agents and Electrolytes in Aqueous Medium", Tenside Surf Det, 1979, 16, 252-261.
  5. I. S. Kang and S. Y. Jung, "Effect of Steric Stability by Adsorption of Surfactant on Detergency of Particulate Soil in Anionic/nonionic Surfactant Mixed Solution (Part 2)- Adsorption of Surfactant to the Fabric and Adhesion of Particle to Fabric-", Text Sci Eng, 2005, 42, 174-181.
  6. I. S. Kang, "Influence of Characteristics of Textile Materials Finished with Hydrophilic and Hydrophobic Chemicals on Detergency of Particulate Soil-the Adsorption of Surfactant to Fabric and ${\zeta}$ potential of Substrate", Text Sci Eng, 2006, 43, 344-352.
  7. I. S. Kang, M. H. Mun, and J. J. Rha, "The Surface Morphology and Characteristics of Poly(ethylene Terephthalate) Film", J Kor Soc Cloth Text, 2010, 34, 1880-1888. https://doi.org/10.5850/JKSCT.2010.34.11.1880
  8. I. S. Kang, "The Effects of Surface Morphology of Poly (ethylene Terephthalate) Film on Detergency of Particulate Soil (II) -Adsorption of Surfactant and Interfacial Phenomena-", Text Sci Eng, 2011, 48, 280-288.
  9. E. Matijevic and P. Scheiner, "Ferric Hydrous Oxide Sols", J Colloid Interface Sci, 1978, 63, 509. https://doi.org/10.1016/S0021-9797(78)80011-3
  10. I. S. Kang and S. R. Kim, "Interfacial Electrical Studies on Adhesion of Hematite Particle to Polyester Fabric and its Removal from the Fabric (Part 2)", J Kor Soc Cloth Text, 1995, 19, 765-773.
  11. M. H. Mun and I. S. Kang, "The Effect of Particle Size on the Detergency of Particulate Soil", J Kor Soc Cloth Text, 2010, 34, 653-662. https://doi.org/10.5850/JKSCT.2010.34.4.653
  12. I. S. Kang and S. Y. Jung, "Effect of Steric Stability by Adsorption of Surfactant on Detergency of Particulate Soil in Anionic/nonionic Surfactant Mixed Solution (Part 1) - Adsorption of Surfactant to the Particles and Removal of Particle from Fabric", Text Sci Eng, 2005, 42, 166-173.