한국수소및신에너지학회논문집 (Journal of Hydrogen and New Energy)

  • 제22권4호
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  • Pages.465-473
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  • 2011
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  • 1738-7264(pISSN)
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  • 2288-7407(eISSN)
한국수소및신에너지학회 (The Korean Hydrogen and New Energy Society)
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회분식 유동층 반응기에서 촉매함량 변화에 따른 WGS 촉매의 반응특성

Reaction Characteristics of WGS Catalyst with Fraction of Catalyst in a Batch Type Fluidized Bed Reactor

  • 투고 : 2011.07.05
  • 심사 : 2011.08.22
  • 발행 : 2011.08.30
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초록

To find the optimum mixing ratio of WGS catalyst with $CO_2$ absorbent for SEWGS process, water gas shift reaction tests were carried out in a fluidized bed reactor using commercial WGS catalyst and sand (as a substitute for $CO_2$ absorbent). WGS catalyst content, gas velocity, and steam/CO ratio were considered as experimental variables. CO conversion increased as the catalyst content increased during water gas shift reaction. Variations of the CO conversion with the catalyst content were small at low gas velocity. However, those variations increased at higher gas velocity. Within experimental range of this study, the optimum operating condition(steam/CO ratio=3, gas velocity = 0.03 m/s, catalyst content=10 wt.%) to get high CO conversion and $CO_2$ capture efficiency was confirmed. Moreover, long time water gas shift reaction tests up to 20 hours were carried out for two cases (catalyst content = 10 and 20 wt.%) and we could conclude that the WGS reactivity at those conditions was maintained up to 20 hours.

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참고문헌

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