한국수소및신에너지학회논문집 (Journal of Hydrogen and New Energy)

  • 제22권2호
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  • Pages.265-273
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  • 2011
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  • 1738-7264(pISSN)
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  • 2288-7407(eISSN)
한국수소및신에너지학회 (The Korean Hydrogen and New Energy Society)
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탄화수소 환원제 변화가 Fe/ZSM5 촉매를 사용하는 탈질 HC-SCR 반응에 미치는 영향

Effect of Change of Hydrocarbon Reductant on HC-SCR over Fe/ZSM5 Catalyst

  • 김성수 (한국에너지기술연구소 폐자원 에너지 센터) ;
  • 김대영 (서강대학교 화공과) ;
  • 오세용 (서강대학교 화공과) ;
  • 유승준 (서남대학교 환경.화공학부) ;
  • 박정환 (순천향대학교 나노화공과) ;
  • 김진걸 (순천향대학교 나노화공과)
  • 투고 : 2011.03.15
  • 심사 : 2011.04.22
  • 발행 : 2011.04.30
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초록

HC-SCR was conducted using Fe/ZSM5 catalyst coated over 200 cpi cordierite in the conditions of atomspheric pressure and $200^{\circ}C-500^{\circ}C$. Among the tested hydrocarbon reductants, isobutane (i-$C_4H_{10}$) showed the highest de-$NO_x$ yield of 69% at $320^{\circ}C$ with the mole ratio of reductant/$NO_x$ =1.0. De-$NO_x$ yield resulted by the change of alkane reductant was increased as the carbon number of alkane reductant was increased. The order of increase of de-$NO_x$ yield was proportional to the order of decrease of bonding energy between C and H of reductant, where the H abstraction step from alkane molecule could be the rate controlling step of HC-SCR.

키워드

참고문헌

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