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Properties of Water Resistant Plywood made with Modified Serum Protein Adhesive

혈장변성접착제를 사용한 내수합판의 특성

  • Kang, Seog-Goo (Department of Bio-based Materials, Chungnam National University) ;
  • Lee, Hwa-Hyoung (Department of Bio-based Materials, Chungnam National University)
  • 강석구 (충남대학교 환경소재공학과) ;
  • 이화형 (충남대학교 환경소재공학과)
  • Received : 2010.08.13
  • Accepted : 2010.10.12
  • Published : 2011.01.25

Abstract

This study was carried out to examine properties of water resistant plywood by using serum protein adhesive which is natural, environment-friendly and human-friendly. For the preparation of the serum protein adhesive, pig blood from slaughterhouse was centrifuged and serum was separated from corpuscles and concentrated to 30% by dry weight basis. This concentrated serum protein was modified with PF resin (50% NVC) with the ratio of 9 : 2.5. Plywood made by this modified serum protein gave 1.21 N/$mm^2$ of dry bonding strength, 0.80 N/$mm^2$ of wet boil bonding strength, 0% of cyclic delamination test value, and 0.025 ppm of HCHO emission, which met the excellent super $E_0$ grade and water resistant plywood.

Keywords

References

  1. 김영식, 이화형. 1996. 페놀수지와 TCA 침전혈분의 혼합접착제가 합판의 성질에 미치는 효과. 한국가구학회지 7(1,2): 87-94.
  2. 노정관. 1995. 합판용 폐놀수지 접착제의 속경화. 목재공학 23(3): 33-39.
  3. 오용성. 1998. 충전제의 종류가 합판용 폐놀수지 접착제에 미치는 효과. 목재공학 26(3): 48-52.
  4. 이화형. 2003. Eo 등급 목질재료제조를 위한 도축혈분의 산처리 침전혈장과 폐놀합성수지와의 공결합접착제에 관한 방법. 특허 제100391829호.
  5. 이화형, 송경빈. 1995. TCA 침전 혈액접착제의 합판제조에 관한 연구. 한국가구학회지 6(1,2): 53-58.
  6. 이화형, 이종신, 장상식. 1996. 합판용 페놀수지 접착제에 대한 TCA침전 혈액분말의 첨가 효과. 목재공학 24(2): 15-19.
  7. 이화형, 한기선. 1997. TCA혈분-폐놀수지가 파티클보드의 성질에 미치는 영향. 한국가구학회 8(1,2): 1-7.
  8. 이화형, 한기선. 1998. HCl로 침전처리한 혈액으로부터의 혈분수지 제조 배합비에 따른 점도변이와 합판 접착력에 미치는 영향. 한국가구학회 9(2): 33-39.
  9. 이화형, 홍승도. 1984. 요소멜라민, 폐놀공축합수지가합판의 재질에 미치는 영향. 목재공학 12(1): 38-43.
  10. 한국산업규격 2006. 보통합판 KS F 3101. 한국표준협회.
  11. Baldwin, R. F. 1975. Plywood Manufacturing Practices. miller Freeman Pub. 260p.
  12. Cho, Y., H. H. Lee, and K. B. Song. 1999. "Preperation of Blood Glue from Procine Plasma Protein and Cross-linking Reaction of Protein with Formaldehyde". Agric. Chem. Biotechnol 42(2): 81-84.
  13. Eichholz, W. 1907. German Patent 199,903 (Aug. 16, 1907).
  14. Detlefsen, W. D. 1989. Blood and casein adhesives for bonding wood. p. 451, Cp. 31 of Adhesives from Renewable Resources. Editor. R. W. Hemingway et al. Americal Chemical Society. 1989.
  15. Hse, C. Y. 1971. Properties of phenolic adhesives as related to bond quality in southern pine plywood. Forest Products Journal 21(1): 44-52.
  16. John, H. 1920. U.S. Patent 1,355,834.
  17. Lambuth, A. L. 1977. Blood glues. p. 190. Handbook of Adhesives. Cp. 11. Blood glues. Editor: I. Skeist, VNR Co. 2nd ed.
  18. Park, E., H. H. Lee, and K. B. Song. 1996. Characterization of plasma proteins from bloods of slaugtered cow and pig and utilization of the proteins as adhesives. Agricultural Chemistry and Biotechnology 39(2): 123-126.
  19. Skeist, I., 1977. Handbook of Adhesives (2nd edition) VNR Co.
  20. Takashima,T., K. Ariga, and M. Chubachi. 1960. Research on blood glue. VIII. On mixed glue of urea formaldehyde resin and blood glue. Mokuzai Gakkaishi 6(4): 165-170.
  21. WHO. 2002. Estimated deaths & DDALYs attribuable to selected environmental risk factors. Department of Public Health & Environment.
  22. Yamashita, S. and Y. Turukichi. 1987. Process for producing blood powder. United States Patent 4666725.
  23. 半井勇三, 森北出版. 1961. 木材の接着と接着劑.
  24. 渡辺治夫, 森北出版, 1962. 合板の 製造.