Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Lithium Insertion Behavior of Nanoscopic Co3O4 Prepared with Avian Egg Membrane as a Template

  • Christy, Maria (School of Semiconductor and Chemical Engineering, and Semiconductor Physics Research Center, Chonbuk National University) ;
  • Jisha, M.R (Specialized Graduate School of Hydrogen and Fuel Cells Engineering, Chonbuk National University) ;
  • Kim, Ae-Rhan (Specialized Graduate School of Hydrogen and Fuel Cells Engineering, Chonbuk National University) ;
  • Nahm, Kee-Suk (School of Semiconductor and Chemical Engineering, and Semiconductor Physics Research Center, Chonbuk National University) ;
  • Yoo, Dong-Jin (Specialized Graduate School of Hydrogen and Fuel Cells Engineering, Chonbuk National University) ;
  • Suh, E.K. (School of Semiconductor and Chemical Engineering, and Semiconductor Physics Research Center, Chonbuk National University) ;
  • Kumari, T. Sri Devi (Electrochemical Power Systems Division, Central Electrochemical Research Institute) ;
  • Kumar, T. Prem (Electrochemical Power Systems Division, Central Electrochemical Research Institute) ;
  • Stephan, A. Manuel (Electrochemical Power Systems Division, Central Electrochemical Research Institute)
  • Received : 2010.11.01
  • Accepted : 2011.02.06
  • Published : 2011.04.20
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Abstract

Nanoscopic $Co_3O_4$ particles were prepared using avian egg membrane as a template at $800^{\circ}C$. The prepared materials were subjected to XRD, SEM, TEM and Raman spectroscopic studies. Cyclic voltammetry study shows a single step oxidation and reduction process. Electrochemical lithium insertion behavior of the materials was examined in coin cells of the 2032 configuration. The material showed a discharge capacity 600mAh/g even after 20 cycles.

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References

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