Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Spectroscopic Properties of Quercetin-3-O-rhamnoside and Quercetin-3-O-rutinoside in Aerosol-OT Reverse Micelles

  • Park, Hyoung-Ryun (Department of Chemistry and Research Institute of Basic Science, Chonnam National University) ;
  • Liu, Hai-Bo (Department of Chemistry, and Research Institute of Life Science, Gyeongsang National University) ;
  • Shin, Sung-Chul (Department of Chemistry, and Research Institute of Life Science, Gyeongsang National University) ;
  • Park, Jong-Keun (Department of Chemical Education, and Research Institute of Life Science, Gyeongsang National University) ;
  • Bark, Ki-Min (Department of Chemical Education, and Research Institute of Life Science, Gyeongsang National University)
  • Received : 2010.12.31
  • Accepted : 2011.01.20
  • Published : 2011.03.20
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Abstract

The anomalous spectroscopic properties of quercetin-3-O-rhamnoside (QCRM) and quercetin-3-O-rutinoside (QCRT) in AOT reverse micelle were studied. The excited state intramolecular proton transfer (ESIPT) occurs through the strong hydrogen bond between the -OH at position 5 and the carbonyl oxygen. Because the ESIPT can only happens in the $S_1$ state and the Franck-Condon factor involved in the $S_2\;{\rightarrow}\;S_1$ internal conversion is small, the $S_2\;{\rightarrow}\;S_o$ emission alone appears. Because the molecular planarity is improved at the interior of the micelle, the excited state intramolecular charge transfer in the $S_1$ state is extended, and the excited state is more tolerable for any quenching effects in the micelle. Therefore, an $S_1\;{\rightarrow}\;S_o$ emission was newly discovered under this micelle microenvironment. For the $S_2\;{\rightarrow}\;S_o$ emission, the quantum yields increase but the quantum yield of the $S_1\;{\rightarrow}\;S_o$ emission approximately decreases as the water concentration in the micelle increases.

Keywords

References

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