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연소열과 화학양론계수를 이용한 에테르류의 폭발한계의 예측

Prediction of Explosion Limits of Ethers by Using Heats of Combustion and Stoichiometric Coefficients

  • 하동명 (세명대학교 보건안전공학과)
  • Ha, Dong-Myeong (Dept. of Occupational Health and Safety Engineering., Semyung University)
  • 투고 : 2011.05.11
  • 심사 : 2011.08.26
  • 발행 : 2011.08.31

초록

폭발한계는 가연성물질의 화재 및 폭발위험성을 결정하는데 주요한 특성치 가운데 하나이다. 본 연구에서, 에테르류의 폭발하한계와 상한계에 대해 연소열과 화학양론계수를 이용하여 예측하였다. 제시된 예측식에 의한 예측값은 문헌값과 적은 오차범위에서 일치하였다. 제시된 방법론을 사용하여 다른 에테르류의 폭발한계 예측이 가능해졌다.

Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower explosion limit(LEL) and upper explosion limit(UEL) of ethers were predicted by using the heat of combustion and stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other flammable ethers.

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