Bulletin of the Korean Chemical Society

  • 제32권2호
  • /
  • Pages.630-634
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Fast, Efficient and Regioselective Conversion of Epoxides to β-Hydroxy Thiocyanates with NH4SCN/Zeolite Molecular Sieve 4 Å under Solvent-Free Conditions

  • 투고 : 2010.11.23
  • 심사 : 2010.12.10
  • 발행 : 2011.02.20
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초록

Solvent-free conversion of various epoxides to their corresponding $\beta$-hydroxy thiocyanates was carried out successfully with $NH_4SCN$/zeolite molecular sieve $4{\AA}$ system at room temperature. The reactions were completed within 2 - 7 min to give thiocyanohydrins with perfect regioselectivity and isolated yields. Moreover, the zeolite can be reused for several times without losing its activity.

키워드

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피인용 문헌

  1. ChemInform Abstract: Fast, Efficient and Regioselective Conversion of Epoxides to β-Hydroxy Thiocyanates with NH4SCN/Zeolite Molecular Sieve 4 Å under Solvent-Free Conditions. vol.42, pp.24, 2011, https://doi.org/10.1002/chin.201124085
  2. Remarkably Fast and Mild Solvent-Free Conversion of Epoxides into Thiocyanohydrins Using Mukaiyama Reagent vol.187, pp.11, 2012, https://doi.org/10.1080/10426507.2012.685670
  3. -Hydroxy Thiocyanates in Water vol.2013, pp.2090-9071, 2013, https://doi.org/10.1155/2013/561649
  4. SCN under solvent-free conditions pp.1563-5325, 2017, https://doi.org/10.1080/10426507.2017.1390460
  5. 1,1'-Bis-Methyl-3, 3-Methylenebisimidazolium Dichloride as an Efficient Phase Transfer Catalyst for Ring Opening of Epoxides Using SCN- and N3- in water vol.36, pp.7, 2011, https://doi.org/10.3184/174751912x13371750612188
  6. Ring Opening of Epoxides by Using Cross-Linked Poly(4-Vinylpyridine)-Supported Thiocyanate in the Presence of Polymer-Supported Sulfuric Acid Under Solvent-Free Conditions vol.190, pp.4, 2015, https://doi.org/10.1080/10426507.2014.887079
  7. A highly efficient protocol for regioselective ring-opening of epoxides with alcohols, water, acetic acid, and acetic anhydride catalyzed by SbF3 vol.191, pp.7, 2011, https://doi.org/10.1080/10426507.2015.1135439
  8. The Application of 4Å Molecular Sieves in Organic Chemical Syntheses: An Overview vol.53, pp.2, 2011, https://doi.org/10.1055/s-0040-1706535