Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Novel Solid Phase Extraction Procedure for Some Trace Elements in Various Samples Prior to Their Determinations by FAAS

  • Sacmaci, Srife (Erciyes University, Department of Chemistry, Faculty of Arts and Sciences) ;
  • Kartal, Senol (Erciyes University, Department of Chemistry, Faculty of Arts and Sciences) ;
  • Sacmaci, Mustafa (Bozok University, Department of Chemistry, Faculty of Arts and Sciences) ;
  • Soykan, Cengiz (Bozok University, Department of Chemistry, Faculty of Arts and Sciences)
  • Received : 2010.08.03
  • Accepted : 2010.11.25
  • Published : 2011.02.20
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Abstract

A novel method that utilizes poly(5-methyl-2-thiozyl methacrylamide-co-2-acrylamido-2-methyl-1-propanesulfonic acid-co-divinylbenzene) [MTMAAm/AMPS/DVB] as a solid-phase extractant was developed for simultaneous preconcentration of trace Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) prior to the measurement by flame atomic absorpiton spectrometry (FAAS). Experimental conditions for effective adsorption of the metal ions were optimized using column procedures. The optimum pH value for the simultaneously separation of the metal ions on the new adsorbent was 2.5. Effects of concentration and volume of elution solution, sample flow rate, sample volume and interfering ions on the recovery of the analytes were investigated. A high preconcentration factor, 100, and low relative standard deviation values, $\leq$1.5% (n = 10), were obtained. The detection limits (${\mu}gL^{-1}$) based on the 3s criterion were 0.18 for Cd(II), 0.11 for Co(II), 0.07 for Cr(III), 0.12 for Cu(II), 0.18 for Fe(III), 0.67 for Mn(II), 0.13 for Ni(II), 0.06 for Pb(II), and 0.09 for Zn(II). The validation of the procedure was performed by the analysis of two certified reference materials. The presented method was applied to the determination of the analytes in various environmental samples with satisfactory results.

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References

  1. Minczewski, J.; Chwastowska, J.; Dybczynski, R. Separation and Preconcentration Method in Inorganic Trace Analysis; Ellis Horwood/Halsted Press: Chichester, 1982; p 26.
  2. Tu, Z.; He, Q.; Chang, X.; Hu, Z.; Gao, R.; Zhang, L.; Li, Z. Anal. Chim. Acta 2009, 649, 252. https://doi.org/10.1016/j.aca.2009.07.042
  3. Kagaya, S.; Maeba, E.; Inoue, Y.; Kamichatani, W.; Kajiwara, T.;Yanai, H.; Saito, M.; Tohda, K. Talanta 2009, 79, 146. https://doi.org/10.1016/j.talanta.2009.03.016
  4. Boevski, I.; Daskalova, U. N.; Havezov, I. Spectrochim. Acta B2000, 55, 1643. https://doi.org/10.1016/S0584-8547(00)00265-2
  5. Atanassova, D.; Stefanova, V.; Russeva, E. Talanta 1998, 47, 1237. https://doi.org/10.1016/S0039-9140(98)00211-2
  6. Nicolai, M.; Rosin, C.; Tousset, N.; Nicolai, Y. Talanta 1999, 50,433. https://doi.org/10.1016/S0039-9140(99)00130-7
  7. Tarleya, C. R. T.; Santosa, V. S.; Baetaa, B. E. L.; Pereirab, A. C.;Kubota, L. T. J. Hazard. Mater. 2009, 169, 256. https://doi.org/10.1016/j.jhazmat.2009.03.077
  8. Duran, C.; Gündogdu, A.; Bulut, V. N.; Soylak, M.; Elci, L.; senturk,H. B.; Tufekci, M. J. Hazard. Mater. 2007, 146, 347. https://doi.org/10.1016/j.jhazmat.2006.12.029
  9. Rao, T. P.; Daniel, S.; Gladis, J. M. Trends Anal. Chem. 2004, 23,28. https://doi.org/10.1016/S0165-9936(04)00106-2
  10. Camel, V. Spectrochim. Acta B 2003, 58, 1177. https://doi.org/10.1016/S0584-8547(03)00072-7
  11. Garg, B. S.; Sharma, R. K.; Bhojak, N.; Mittal, S. Microchem J.1999, 61, 94. https://doi.org/10.1006/mchj.1998.1681
  12. Kantipuly, C.; Atragadda, S. K.; Chow, A.; Gesser, H. D. Talanta1990, 37, 491. https://doi.org/10.1016/0039-9140(90)80075-Q
  13. Sharma, R. K.; Pant, P. J. Hazard. Mater. 2009, 163, 295. https://doi.org/10.1016/j.jhazmat.2008.06.120
  14. Mashhadizadeh, M. H.; Pesteh, M.; Talakesh, M.; Sheikhshoaie, I.;Ardakani, M. M.; Karimi, M. A. Spectrochim. Acta B 2008, 63,885. https://doi.org/10.1016/j.sab.2008.03.018
  15. Zougagh, M.; Pavón, J. M. C.; Torres, A. G. Anal. Bioanal. Chem.2005, 381, 1103. https://doi.org/10.1007/s00216-004-3022-2
  16. Sacmaci, s.; Saçmacı, M.; Soykan, C.; Kartal, S. J. Macromol. Sci.A 2010, 47, 552. https://doi.org/10.1080/10601321003742055
  17. Azab, M. M. J. Polym. Res. 2005, 12, 9. https://doi.org/10.1007/s10965-004-0655-y
  18. Stieber, F.; Mazitschek, R.; Soric, N.; Giannis, A; Waldmann, H.Angew. Chem. Int. Ed. 2002, 41, 4757. https://doi.org/10.1002/anie.200290040
  19. Alan, M.; Kara, D.; Fisher, A. Sep. Sci. Technol. 2007, 42, 879. https://doi.org/10.1080/01496390601174182
  20. Venkatesh, G.; Jain, A.K.; Singh, A. K. Microchim. Acta 2005,149, 213. https://doi.org/10.1007/s00604-005-0320-0
  21. Ghaedi, M.; Niknam, K.; Shokrollahi, A.; Niknam, E.; Ghaedi, H.;Soylak, M. J. Hazard. Mater. 2008, 158, 131. https://doi.org/10.1016/j.jhazmat.2008.01.037

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