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Evaluation and Comparative Physical/Biological Removal Performance for Extremely Low-Concentration NDMA(N-nitrosodimethylamine)

극저농도 NDMA(N-nitrosodimethylamine) 물리적/생물학적 처리 효율 비교 평가

  • 박세용 (한양대학교 건설환경공학과) ;
  • 김희주 (한양대학교 건설환경공학과) ;
  • 김문일 (한양대학교 건설환경공학과)
  • Received : 2010.11.17
  • Accepted : 2010.12.21
  • Published : 2011.02.01

Abstract

NDMA(N-Nitrosodimethylamine) has been considered as a carcinogenic pollutant even at extremely low-concentration (10ng/L). However, previous researches on NDMA have focused on mainly high concentration due to a difficulty of analysis. In this study, removal efficiencies were evaluated for individual or combined methods with PAC(Powder Activated Carbon), GS(Granular Sludge), MF(Microfiltration), UF(Ultrafiltration) and Silica gel(MCM-41, Diatomite, Spherical silica gel) at both aerobic and anaerobic conditions. Combined method of GS, PAC and UF membrane at anaerobic condition showed the highest removal efficiency of 65% while Silica gel showed the lowest removal efficiency of 6%. The outcomes of this study could be used further study of extremely low-concentration NDMA removal.

NDMA(N-Nitrosodimethylamine)는 극저농도(10ng/L)에서도 암을 일으킬 수 있는 물질로 알려져 있지만, 기존의 NDMA 제거율 평가 연구는 고농도의 NDMA를 대상으로 한 것이 대부분이었다. 따라서 극저농도의 NDMA 제거효율 평가가 필요하며 그 기초연구로써 호기성/혐기성 조건에서의 분말활성탄, GS(Granular Sludge), MF(Microfiltration), UF(Ultrafiltration)를 이용한 제거효율과 Silica gel(MCM-41, Diatomite, Spherical silica gel)을 이용한 제거효율을 평가하였다. 그 결과 혐기성 조건에서 GS, PAC를 접촉한 후 UF membrane을 이용한 고액분리가 65%의 제거율로 가장 높았으며, Silica gel(MCM-41)이 6%의 제거율로 가장 낮았다. 본 연구는 극저농도의 NDMA 제거의 기초 연구로서 향후 관련 연구의 기초자료로써 활용을 기대한다.

Keywords

Acknowledgement

Supported by : 한국연구재단

References

  1. 손희종(2005), 염소소독 부산물의 생성특성과 고도정수처리에 의한 제어, 박사학위논문, 부경대학교, pp. 21-22.
  2. 이만호(2006), 분리막과 전해소독장치를 이용한 정수처리공정 연구, 박사학위논문, 서울시립대학교, pp. 1-4.
  3. 이성범(2008), Nitrosodimethylamin의 저농도 정량법과 물리. 화학적 처리, 석사학위논문, 한양대학교, pp. 23.
  4. 이성범, 윤여민, 최창규, 정진욱, 이용우, 박세용, 김문일(2008), 극미량 농도 물질의 측정 및 활성탄 흡착 처리, 대한환경공학회지, Vol. 30. No. 9, pp. 913-917.
  5. California Department of Health Services(2002), NDMA in California Drinking Water 15, http://www.dhs.ca.gov/ps/ddwem/ chemicals/NDMA/history.htm.
  6. Fournier, D., Haware, J., Streger, S.H., Mcclay, K. and Hatzinger, B.(2006), Biotransformatrion of N-Nitrosodimethylamine by Pseudomonas Mendocina KR1., Applied and Environmental Microbiology, Vol. 72, No. 10, pp. 6693-9998. https://doi.org/10.1128/AEM.01535-06
  7. Jeffrey W. A. Charrois, Hrudey, S. E.(2007), Breakpoint Chlorination and Free-Chlorine Contact Time: Implications for Drinking Water N-Nitrosodimethylamine Concentrations, Water Research, Vol. 41, Issue 3, pp. 674-682. https://doi.org/10.1016/j.watres.2006.07.031
  8. Jobb, D. B., Hunsinger, R. B., Meresz, O., Taguchi, V.(1994), Removal of N-nitrosodimethylamine from the Ohsweken Water Supply Final Report, Toronto, Ontario Ministry of Environmental and Energy, Science and Technology Branch(ISBN 0-7778-3439-1), pp. 1-11.
  9. Karen L. Simson and Keith P. Hayes(1998), Drinking Water Disinfection by Products : An Australian Perspective, Water Research, Vol. 32, Issue 5, pp. 1522-1528. https://doi.org/10.1016/S0043-1354(97)00341-2
  10. Mitch, W. A., Grercke, A. C., Sedlak, D. L.(2003), A Nnitrosodimethylamine (NDMA) Precursor Analysis for Chlorination of Water and Wastewater, Water Research, Vol. 37, Issue 15, pp. 3733-3741. https://doi.org/10.1016/S0043-1354(03)00289-6
  11. Mitch, W. A., Sharp, J. O., Trussell, R. R, Valentine, R. L., Alvarez-Cohen, L., Sedlak, D. L.(2003), N-nitroso-dimethylamine (NDMA) as a Drinking Water Contaminant : A Review, Environmental Engineering Science. Vol. 20, No. 5, pp. 389- 404. https://doi.org/10.1089/109287503768335896
  12. Murray, C. A., Parsons, S. A.(2004), Removal of NOM from Drinking Water: Fenton's and Photo-Fenton's Processes, CHEMOSPHERE, Vol 54, Issue 7, pp. 1017-1023. https://doi.org/10.1016/j.chemosphere.2003.08.040
  13. Rehan Sadiq and Rodrighez, M. J.(2004), Disinfection by Products (DBPs) in Dinking Water and Predictive Models for Their Occurrence: a Review, Science of The Total Environment, Vol. 321, Issue 1-3, pp. 21-46. https://doi.org/10.1016/j.scitotenv.2003.05.001
  14. Richardson, S. D.(2003), Disinfection by-Products and Other Emerging Contaminants in Drinking Water, Trends in Analytical Chemistry, Vol. 22 No. 10, pp. 666-684. https://doi.org/10.1016/S0165-9936(03)01003-3
  15. Schafer, A. I., Schwicker, U., Fischer, M. M., Fane, A. G. and Waite, T. D.(2000), Microfiltration of Colloids and Natural Organic Matter, Journal of Membrane Science, Vol 171, Issue 2, pp. 151-172. https://doi.org/10.1016/S0376-7388(99)00286-0
  16. Sharp, J. O., Sales, C. M., Leblanc, J. C., Jie Liu, Wood, T. K., Eltis, L. D., Mohn, W. W., Lisa Alvarez-Cohen(2007), An Inducible Propane Monooxygenase is Responsible for N-Nitrosodimethylamine Degradation by Rhodococcus sp. RHA1, Applied and Environmental Microbiology, Vol. 73, No. 21, pp. 6930- 6938. https://doi.org/10.1128/AEM.01697-07
  17. Sharp, J. O., Wood, T. K. and Alvarez-Cohen, L.(2005), Aerobic Biodegradation of N-nitrosodimethylamine (NDMA) by Axenic Bacterial Strains, Biotechnology Bioengineering, Vol. 89, No. 5, pp. 608-618. https://doi.org/10.1002/bit.20405
  18. United States Environmental Protection Agency(EPA)(2004), Intergrated Risk Information System(IRIS), Office of Research and Development(ORD), http://www.epa.gov/iris/subst/0045.htm.
  19. Yoshinari, T., and Shafer, D.(1990), Degradation of Dimethyl Nitrosamine by Methylosinus Trichosporium OB3b, Canadian Journal of Microbiol. Vol. 36, No. 12, pp. 834-838. https://doi.org/10.1139/m90-144