Clean Technology (청정기술)

The Korean Society of Clean Technology (한국청정기술학회)
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Recent Development to Generate Carbon Dioxide-based Cyclic Carbonate and Polycarbonate

이산화탄소기반 고리형 카보네이트 및 폴리카보네이트 제조 연구 동향

  • Kwon, Doo-Yeon (Department of Molecular Science and Technology, Ajou University) ;
  • Kim, Jae-Il (Department of Molecular Science and Technology, Ajou University) ;
  • Kang, Hwi-Ju (Department of Molecular Science and Technology, Ajou University) ;
  • Kim, Da-Yeon (Department of Molecular Science and Technology, Ajou University) ;
  • Kim, Jae-Ho (Department of Molecular Science and Technology, Ajou University) ;
  • Lee, Bong (Department of Polymer Engineering, Pukyong National University) ;
  • Kim, Moon-Suk (Department of Molecular Science and Technology, Ajou University)
  • 권두연 (아주대학교 분자과학기술학과) ;
  • 김재일 (아주대학교 분자과학기술학과) ;
  • 강휘주 (아주대학교 분자과학기술학과) ;
  • 김다연 (아주대학교 분자과학기술학과) ;
  • 김재호 (아주대학교 분자과학기술학과) ;
  • 이봉 (부경대학교 고분자공학과) ;
  • 김문석 (아주대학교 분자과학기술학과)
  • Received : 2011.07.14
  • Accepted : 2011.09.16
  • Published : 2011.09.30
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Abstract

The green house gas, carbon dioxide, can be utilized as raw materials to prepare carbon dioxide-based polycarbonates in research and industry. The carbon dioxide-based polycarbonates is one of the emerging low-cost green polymers. Recently, the fast development of carbon dioxide-based polycarbonates has created new chances for industry. In this review, we describe the preparation and characterization of cyclic carbonate monomer using carbon dioxide, oxiranes and oxetanes in the presence of various catalysts and preparation of polycarbonates from cyclic carbonate monomer, presenting an organized and detailed overview of the state of the art.

온실효과 유발 이산화탄소는 학문적, 산업적 관점에서 이산화탄소 기반 폴리카보네이트 제조에 대한 원료로서 적용 가능하다. 그러므로 이산화탄소 기반 폴리카보네이트는 탁월한 경제적 녹색고분자이다. 최근 이산화탄소 기반 폴리카보네이트의 빠른 개발이 산업적으로 새로운 기회를 제공하고 있다. 본 총설에서는 다양한 촉매 존재하에서 이산화탄소 및 에폭사이드 계열 화합물을 이용한 고리형 카보네이트 모노마 제조 및 제조된 모노마로부터 이산화탄소 기반 폴리카보네이트 제조에 대한 연구 동향을 설명하고자 한다.

Keywords

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