Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

A Facile Synthetic Method of Silver Nanoparticles with a Continuous Size Range from sub-10 nm to 40 nm

  • Piao, Longhai (Department of Chemistry, Kongju National University) ;
  • Lee, Kyung-Hoon (Department of Bio & Nano Chemistry, Kookmin University) ;
  • Min, Byoung-Koun (Department of Clean Energy Research Center, Korea Institute of Science and Technology) ;
  • Kim, Woong (Department of Materials Science and Engineering, Korea University) ;
  • Do, Young-Rag (Department of Bio & Nano Chemistry, Kookmin University) ;
  • Yoon, Sung-Ho (Department of Bio & Nano Chemistry, Kookmin University)
  • Received : 2010.09.04
  • Accepted : 2010.10.30
  • Published : 2011.01.20
Download PDF
⟨ Previous Next ⟩

Abstract

Size-controlled Ag nanoparticles (NPs) were prepared from the decomposition of Ag(I) carboxylates using ethanolamine derivatives as a reducing agent without an additional stabilizing agent. The size of the Ag NPs with a narrow size distribution (sub-10 nm to ca. 40 nm) was controlled precisely by varying the processing parameters, such as the type of reducing agent and the chain length of the carboxylate in the Ag(I) carboxylate. The optical properties, surface composition and crystallinity of the Ag NPs were characterized by ultraviolet-visible spectroscopy, gas chromatography-mass spectrometry, thermal gravimetric analysis, transmission electron microscopy and X-ray diffraction.

Keywords

References

  1. Bell, A. T. Science 2003, 299, 1688. https://doi.org/10.1126/science.1083671
  2. Goddard, W. A.; Brenner, D. W.; Lyshevski, S. E.; Iafrate, G. J. Handbook of Nanoscience, Engineering, and Technology, 2nd ed.; CRC Press: FL, 2007.
  3. Rosi, N. L.; Mirkin, C. A. Chem. Rev. 2005, 105, 1547. https://doi.org/10.1021/cr030067f
  4. Puntes, V. F.; Krishnan, K. M.; Alivisatos, A. P. Science 2001, 291, 2115. https://doi.org/10.1126/science.1057553
  5. Burda, C.; Chen, X. B.; Narayanan, R.; El-Sayed, M. A. Chem. Rev. 2005, 105, 1025. https://doi.org/10.1021/cr030063a
  6. Milliron, D. J.; Hughes, S. M.; Cui, Y.; Manna, L.; Li, J. B.; Wang, L. W.; Alivisatos, A. P. Nature 2004, 430, 190. https://doi.org/10.1038/nature02695
  7. Cozzoli, P. D.; Comparelli, R.; Fanizza, E.; Curri, M. L.; Agostiano, A.; Laub, D. J. Am. Chem. Soc. 2004, 126, 3868. https://doi.org/10.1021/ja0395846
  8. Zhang, W.; Qiao, X. J. Chen, Mater. Sci. Eng. B 2007, 142, 1. https://doi.org/10.1016/j.mseb.2007.06.014
  9. Bronstein, L. M.; Kostylev, M.; Shtykova, E.; Vlahu, T.; Huang, X.; Stein, B. D.; Bykov, A.; Remmes, N. B.; Baxter, D. V.; Svergun, D. I. Langmuir 2008, 24, 12618. https://doi.org/10.1021/la8021276
  10. Scott, R. W. J.; Wilson, O. M.; Crooks, R. M. J. Phys. Chem. B 2005, 109, 692. https://doi.org/10.1021/jp0469665
  11. Brinas, R. P.; Hu, M. H.; Qian, L. P.; Lymar, E. S.; Hainfeld, J. F. J. Am. Chem. Soc. 2008, 130, 975. https://doi.org/10.1021/ja076333e
  12. Jana, N. R.; Gearheart, L.; Murphy, C. J. Langmuir 2001, 17, 6782. https://doi.org/10.1021/la0104323
  13. Liu, Y. C.; Lin, L. H.; Chiu, W. H. J. Phys. Chem. B 2004, 108, 19237. https://doi.org/10.1021/jp046866z
  14. van Osch, T. H. J.; Perelaer, J.; de Laat, A. W. M.; Schubert, U. S. Adv. Mater. 2008, 20, 343. https://doi.org/10.1002/adma.200701876
  15. Rozenberg, G. G.; Bresler, E.; Speakman, S. P.; Jeynes, C.; Steinke, J. H. G. Appl. Phys. Lett. 2002, 81, 5249. https://doi.org/10.1063/1.1481985
  16. Smith, P. J.; Shin, D.-Y.; Stringer, J. E.; Derby, B.; Reis, N. J. Mater. Sci. 2006, 41, 4153. https://doi.org/10.1007/s10853-006-6653-1
  17. Chung, J.; Ko, S.; Bieri, N. R.; Grigoropoulos, C. P.; Poulikakos, D. Appl. Phys. Lett. 2004, 84, 801. https://doi.org/10.1063/1.1644907
  18. Buffat, Ph.; Borel, J. P. Phys. Rev. A 1976, 13, 2287. https://doi.org/10.1103/PhysRevA.13.2287
  19. Luo, W.; Hu, W.; Xiao, S. J. Phys. Chem. C 2008, 112, 2359. https://doi.org/10.1021/jp0770155
  20. Komarneni, S.; Li, D. S.; Newalkar, B.; Katsuki, H.; Bhalla, A. S. Langmuir 2002, 18, 5959. https://doi.org/10.1021/la025741n
  21. Skrabalak, S. E.; Wiley, B. J.; Kim, M.; Formo, E. V.; Xia, Y. N. Nano. Lett. 2008, 8, 2077. https://doi.org/10.1021/nl800910d
  22. Socol, Y.; Abramson, O.; Gedanken, A.; Meshorer, Y.; Berenstein, L.; Zaban, A. Langmuir 2002, 18, 4736. https://doi.org/10.1021/la015689f
  23. Shankar, S. S.; Rai, A.; Ahmad, A.; Sastry, M. J. Colloid Interface Sci. 2004, 275, 496. https://doi.org/10.1016/j.jcis.2004.03.003
  24. Kumar, A.; Vemula, P. K.; Ajayan, P. M.; John, G. Nat. Mater. 2008, 7, 236. https://doi.org/10.1038/nmat2099
  25. Hornebecq, V.; Antonietti, M.; Cardinal, T.; Treguer-Delapierre, M. Chem. Mater. 2003, 15, 1993. https://doi.org/10.1021/cm021353v
  26. Yamamoto, M.; Nakamoto, M. J. Mater. Chem. 2003, 13, 2064. https://doi.org/10.1039/b307092a
  27. Kashiwagi, Y.; Yamamoto, M.; Nakamoto, M. J. Colloid Interface Sci. 2006, 300, 169. https://doi.org/10.1016/j.jcis.2006.03.041
  28. Yamamoto, M.; Kashiwagi, Y.; Nakamoto, M. Langmuir 2006, 22, 8581. https://doi.org/10.1021/la0600245
  29. Abe, K.; Hanada, T.; Yoshida, Y.; Tanigaki, N.; Takiguchi, H.; Nagasawa, H.; Nakamoto, M.; Yamaguchi, T.; Yase, K. Thin Solid Films 1998, 327-329, 524. https://doi.org/10.1016/S0040-6090(98)00702-0
  30. Cowdery-Corvan, P. J.; Whitcomb, D. R. In Photothermographic and Thermographic Imaging Materials, Handbook of Imaging Materials, 2nd ed.; Diamond, A. S., Weiss, D. S., Eds.; Marcel-Dekker: NY, 2002.
  31. Mishchenko, M. I.; Travis, L. D.; Lacis, A. A. Scattering, Absorption, and Emission of Light by Small Particles; Cambridge University Press: Cambridge, UK, 2002.
  32. Smakula, A.; Kalnajs, J. Phys. Rev. 1955, 99, 1737. https://doi.org/10.1103/PhysRev.99.1737
  33. Wang, Z. L. J. Phys. Chem. B 2000, 104, 1153. https://doi.org/10.1021/jp993593c
  34. Marks, L. D. Rep. Prog. Phys. 1994, 57, 603. https://doi.org/10.1088/0034-4885/57/6/002
  35. Tang, Y.; Ouyang, M. Nat. Mater. 2007, 6, 754. https://doi.org/10.1038/nmat1982
  36. Zheng, J.; Ding, Y.; Tian, B.; Wang, Z. L.; Zhuang, X. J. Am. Chem. Soc. 2008, 130, 10472. https://doi.org/10.1021/ja803302p
  37. Porta, F.; Krpetic, Z.; Prati, L.; Gaiassi, A.; Scari, G. Langmuir 2008, 24, 7061. https://doi.org/10.1021/la8008392

Cited by

  1. Synthesis of Silver Nanoparticles from the Decomposition of Silver(I) [bis(alkylthio)methylene]malonate Complexes vol.33, pp.1, 2012, https://doi.org/10.5012/bkcs.2012.33.1.60