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초소형 회로보호용 적층 PTC 써미스터의 출발원료 및 Sr 첨가에 따른 전기적 특성

The Electrical Properties of the Laminated PTC Thermistor for Micro Circuit Protection as a Function of Starting Material and Sr Addition

  • 이미재 (한국세라믹기술원 전자광소재센터) ;
  • 김빛남 (한국세라믹기술원 전자광소재센터) ;
  • 황종희 (한국세라믹기술원 전자광소재센터) ;
  • 김진호 (한국세라믹기술원 전자광소재센터) ;
  • 박성철 ((주)이노칩테크놀로지) ;
  • 송준백 ((주)이노칩테크놀로지)
  • Lee, Mi-Jai (Electronic Materials Laboratory, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Bit-Nan (Electronic Materials Laboratory, Korea Institute of Ceramic Engineering and Technology) ;
  • Hwang, Jong-Hee (Electronic Materials Laboratory, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Jin-Ho (Electronic Materials Laboratory, Korea Institute of Ceramic Engineering and Technology) ;
  • Park, Seong-Chul (Annexed Research Institute, InnoChips Technology) ;
  • Song, Jun-Baek (Annexed Research Institute, InnoChips Technology)
  • 투고 : 2011.10.11
  • 심사 : 2011.11.14
  • 발행 : 2011.11.30

초록

We investigated the electrical properties the starting material and sintering condition on the laminated PTC thermistor for micro circuit protection. The influences of $BaTiO_3$ powder with the 0.3 and 0.45 ${\mu}m$ size and the electrical characteristics (Ba,Sr)$TiO_3$ sintered at 1350~1400$^{\circ}C$ for 2 h in a reducing atmosphere (1% $H_2/N_2$). The sintered (Ba,Sr)$TiO_3$ was increased pore and the grain size was decreased according to increasing Sr additions. In relative permittivity, the phase transition temperature of (Ba,Sr)$TiO_3$ was decreased for 2.5$^{\circ}C$ according to increasing 0.01 mole Sr additions, and the phase transition dose not appeared about 0.3 mole Sr addition. The (Ba,Sr)$TiO_3$ was show the low resistance from 0.01 mole to 0.05 mole by Sr addition, regardless of sintering temperature. The (Ba,Sr)$TiO_3$ was show $10^2$ jump order at 0.1 and 0.2 mole Sr addition, and PTCR of the sintered $(Ba_{0.7}Sr_{0.3})TiO_3$ does not appeared about 0.3 mole Sr addition, regardless of the sintering temperature and starting material size.

키워드

참고문헌

  1. M. Valant, D. Suvorov, R. C. Pullar, K. Sarama, and N. M. Alford, "A Mechanism for Low-temperature Sintering," J. Eur. Ceram. Soc., 26 2777-783 (2006). https://doi.org/10.1016/j.jeurceramsoc.2005.06.026
  2. G. Desgardin, P. Bajolet, and B. Raveau, "Barium Titanate Perovskite Sintered with Lithium Fluoride," J. Am. Ceram. Soc., 66 [11] 801-807 (1983). https://doi.org/10.1111/j.1151-2916.1983.tb10566.x
  3. J. Qi, W. Chen, H. Wang, Y. Wang, L. Li, H. Lai, and W. Chan, "Low Temperature Sintering Behavior of $B_2O_3$ Vapor in $BaTiO_3$-Based PTCR Thermistors," Sensor Actuators A., 116 215-18 (2004). https://doi.org/10.1016/j.sna.2004.03.064
  4. D. A. Tolino and J. B. Blum, "Effect of Ba:Ti Ratio on Densification of LiF-Fluxed $BaTiO_3$," J. Am. Ceram. Soc., 68 [11] 292-94 (1985).
  5. J. H. Moon, K. Kim, S. H. Kim, and Y. Kim, "Influences of $Nb_2O_5$ and MnO Addition on the Electrical Properties of $Pb_{0.6}Sr_{0.4}TiO_{3}$ Semiconducting Ceramics," J. Kor. Ceram. Soc., 37 [10] 968-74 (2000).
  6. Y. K. Chung and S. C. Choi, "Effects of the Re-oxidation Temperature and Time on the PTC Properties of Sm-doped $BaTiO_3$," J. Kor. Ceram. Soc., 46 [3] 330-35 (2009). https://doi.org/10.4191/KCERS.2009.46.3.330
  7. C. K. Liang and C. C. Tsai, "Evaluatin of a Novel PTC Theristor for Telecom Overcurrent Protection," Sensors Actuators A, 121 443-49 (2005). https://doi.org/10.1016/j.sna.2005.04.005
  8. L. Affleck and C. Leach, "Micirstructures of $BaTiO_3$ Based PTC Thermistors with Ca, Sr and Pb Additions," J. Eur. Ceram. Soc., 25 3017-3020 (2005). https://doi.org/10.1016/j.jeurceramsoc.2005.03.178
  9. M. Hrvat, D. Belavic, J. Kita, J. Holc, J. Cilensek, L. Golonka, and A. Dziedzic, "Thick-film PTC Thermistors and LTCC Structures: The Dependence of the Electrical and Microstructural Characterisics on the Firing Temperature," J. Eur. Ceram. Soc., 27 2237-43 (2007). https://doi.org/10.1016/j.jeurceramsoc.2006.08.005

피인용 문헌

  1. Electric Properties of the Laminate Type PTC(Positive Temperature Coefficient of Resistance) Thermistor According to Polymer Blowing Agent vol.22, pp.12, 2012, https://doi.org/10.3740/MRSK.2012.22.12.658
  2. PTCR ceramics produced from ultrasound activated barium titanate powders vol.49, pp.11, 2013, https://doi.org/10.1134/S0020168513110083
  3. 적층 SMD형 PTC 써미스터의 열처리 조건에 따른 PTCR 특성 변화 vol.49, pp.5, 2011, https://doi.org/10.4191/kcers.2012.49.5.432