Bulletin of the Korean Chemical Society

  • 제32권11호
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  • Pages.3959-3962
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  • 2011
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Simple Ratiometric Fluorophore for the Selective Detection of Mercury through Hg(II)-Mediated Oxazole Formation

  • Lee, Hee-Jin (Department of Chemistry, Hankuk University of Foreign Studies) ;
  • Kim, Hae-Jo (Department of Chemistry, Hankuk University of Foreign Studies)
  • 투고 : 2011.08.22
  • 심사 : 2011.09.09
  • 발행 : 2011.11.20
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초록

A simple propargylamide-fuctionalized chemodosimeter was prepared for the ratiometric fluorescence detection of mercuric ions in HEPES buffer. The chemodosimeter exhibited $Hg^{2+}$-induced propargyl amide-tooxazole transformation, with a significant accompanying ratiometric change in fluorescence. It afforded high selectivity for mercuric ion detection without any competitive inhibition by common alkali, alkaline earth, or other transition metal ions. The probe showed a $17{\times}10^{-6}M$ detection limit for $Hg^{2+}$ ions and potential applicability for detecting aqueous $Hg^{2+}$ ions.

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피인용 문헌

  1. -propargylamides vol.16, pp.38, 2018, https://doi.org/10.1039/C8OB01474D
  2. Transition Metal-Mediated Synthesis of Oxazoles vol.89, pp.11, 2011, https://doi.org/10.3987/rev-14-808