Bulletin of the Korean Chemical Society

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Polystyrene Supported Al(OTf)3: an Environmentally Friendly Heterogeneous Catalyst for Friedel-Crafts Acylation of Aromatic Compounds

  • Received : 2010.07.21
  • Accepted : 2010.08.23
  • Published : 2010.11.20
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Abstract

Stable and non-hygroscopic polystyrene supported aluminium triflate (Ps-$Al(OTf)_3$), which is prepared easily from cheap and commercially available compounds was found to be an environmentally friendly heterogeneous catalyst for Friedel-Crafts acylation of arenes using acid chlorides in the absence of solvent under mild reaction conditions. The catalyst can be reused up to five times after simple washing with dichloromethane.

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References

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