DOI QR코드

DOI QR Code

The Analytical Bias of Total Hydrocarbon (THC) Measurements in Relation to the Selection of Standard Gas Compound

총탄화수소의 계측에서 표준시료성분의 선택에 따른 오차 발생 연구

  • Kim, Ki-Hyun (Department of Environment & Energy, Sejong University)
  • 김기현 (세종대학교 환경에너지융합학과)
  • Received : 2010.04.23
  • Accepted : 2010.08.04
  • Published : 2010.08.31

Abstract

In this article, the performance of the THC analyzer was inspected using two different span gases of methane ($CH_4$) and propane ($C_3H_8$). To explore the effect of standard gas selection, MicroFID system was tested by the following procedures. Initially, the system is spanned by propane gas of 60 ppm (or 180 ppmC). The system is then run against methane standards prepared at 5 different concentrations of 200, 250, 300, 400, and 500 ppm. According to the suggestion of the KMOE's test procedure to use multiplying a factor of 3 (for propane), the resulting THC values derived by methane standards were systematically biased with ~500% error relative to true value. This paper discusses the interpretation procedures to obtain the least biased THC values for a given span set-up.

Keywords

References

  1. 국립환경과학원(2005) 총탄화수소(THC) 측정기 형식승인 현황. 대기오염, 소음, 진동 공정시험방법(2003) 동화기술편집부편.
  2. Dubose, D.A. and G.E. Harris (1981) Response Factors of VOC Analyzers at a Meter Reading of 10,000 ppmv for Selected Organic Compounds. U.S. Environmental Protection Agency, Research Triangle Park, NC. Publication No. EPA 600/2-81051. September 1981.
  3. Hennigan, S. (1993) Method 21 monitors fugitive emissions, Environmental Protection, 4(9), 26-31.
  4. Jung, K.-Y., K.-H. Kim, and M.-S. Im (2006) Comparative analysis on the relative performance of total hydrocarbon (THC) analyzers: A case study on TVA-1000 vs. MicroFID, J. of the Korean Society for Environmental Analysis, 9(4), 250-254. (in Korean with English abstract)
  5. Kim, M.-Y. and K.-H. Kim (2003) The long-term variation patterns of atmospheric mercury in Seoul, Korea from 1997 to 2002. J. Korean Soc. Atmos. Environ., 19(2), 179-189. (in Korean with English abstract)
  6. Pandey, S.K. and K.-H. Kim (2009) A review of methods for the determination of reduced sulfur compounds (RSCs) in air, Environ. Sci. & Tech., 29, 3020-3029.