Numerical Study of Hydrogen Absorption in a Metal Hydride Hydrogen Storage Vessel

금속수소화물 수소 저장 용기 내부의 수소흡장에 대한 수치해석적 연구

  • Received : 2010.07.19
  • Accepted : 2010.08.20
  • Published : 2010.08.31

Abstract

In this paper, a three-dimensional hydrogen absorption model is developed to precisely study hydrogen absorption reaction and resultant heat and mass transport phenomena in metal hydride hydrogen storage vessels. The 3D model is first experimentally validated against the temperature evolution data available in the literature. In addition to model validation, the detailed simulation results shows that at the initial absorption stage, the vessel temperature and H/M ratio distributions are uniform throughout the entire vessel, indicating that the hydrogen absorption is so efficient during the early hydriding process and thus local cooling effect is not influential. On the other hand, nonuniform distributions are predicted at the latter absorption stage, which is mainly due to different degrees of cooling between the vessel wall and core regions. This numerical study provides the fundamental understanding of detailed heat and mass transfer phenomena during hydrogen absorption process and further indicates that efficient design of storage vessel and cooling system is critical to achieve fast hydrogen charging and high hydrogen storage efficiency.

Keywords

References

  1. 노순영, 이영우, 강경석, 최상진, 김종욱, "수소저장 기술특성 및 특허분석에 의한 기술동 향", 한국수소 및 신에너지학회 논문집, Vol. 19, No. 1, 2008, pp. 90-102.
  2. 심규성, 한상도, 김종원, 명광식, "수소저항합금을 사용한 열저장 및 이용시스템 연구", 태양에너지, Vol. 18, No. 3, 1998, pp. 169-175.
  3. A. Jemni and S. Ben Nasrallah, "Study of two-dimensional heat and mass transfer during absorption in a metal-hydrogen reactor", Int. J. Hydrogen Energ., Vol. 20, No. 1, 1995, pp. 43-52. https://doi.org/10.1016/0360-3199(93)E0007-8
  4. S. Ben Nasrallah and A. Jemni, "Heat and mass transfer models in metal-hydrogen reactor", Int. J. Hydrogen Energ., Vol. 22, No. 1, 1997, pp. 67-76. https://doi.org/10.1016/S0360-3199(96)00039-0
  5. M. Ram Gopal and S. Srinivasa Murthy, "Studies on heat and mass transfer in metal hydride beds", Int. J. Hydrogen Energ., Vol. 20, No. 1, 1995, pp. 911-917. https://doi.org/10.1016/0360-3199(95)00026-A
  6. G. Mohan, M. Prakash Maiya and S. Srinivasa Murthy, "Performance simulation of metal hydride hydrogen storage device with embedded filters and heat exchanger tubes", Int. J. Hydrogen Energ., Vol. 32, 2007, pp. 4978-4987. https://doi.org/10.1016/j.ijhydene.2007.08.007
  7. A. Kumar phate, M. Prakash Maiya and S. Srinivasa Murthy, "Simulation of transient heat and mass transfer during hydrogen sorption in cylindrical metal hydride beds", Int. J. Hydrogen Energ., Vol. 32, 2007, pp. 1969-1981. https://doi.org/10.1016/j.ijhydene.2006.09.020
  8. U. Mayer, M. Groll and W. Supper, "Heat and mass transfer in metal hydride reaction beds: Experimental and theoretical results", J. Less- Comm. Met., Vol. 131, 1987, pp. 235-244. https://doi.org/10.1016/0022-5088(87)90523-6
  9. C. A. Chung and C. J. Ho, "Thermal-fluid behavior of the hydriding and dehydriding processes in a metal hydride hydrogen storage canister", Int. J. Hydrogen Energ., Vol. 34, 2009, pp. 4351-4364. https://doi.org/10.1016/j.ijhydene.2009.03.028
  10. A. Jemni, S. Ben Nasrallah and J. Lamloumi, "Experimental and theoretical study of a metalhydrogen reactor", Int. J. Hydrogen Energ., Vol. 24, 1999, pp. 631-644. https://doi.org/10.1016/S0360-3199(98)00117-7