강수 함유 자성물질에 대한 환경자기학적 분석

Magnetic Particles in Rainfalls: An Environmental Magnetic Evaluation

  • 암알잘갈 (충남대학교 지질환경과학과) ;
  • 유용재 (충남대학교 지질환경과학과)
  • Baatar, Amarjargal (Department of Geology and Earth Environmental Sciences, Chungnam National University) ;
  • Yu, Yong-Jae (Department of Geology and Earth Environmental Sciences, Chungnam National University)
  • 투고 : 2010.06.04
  • 심사 : 2010.06.16
  • 발행 : 2010.06.30

초록

금번 연구에서는 2009년 1월 1일부터 12월 31일 사이에 대전광역시 유성구 지역에서 확보한 강수 시료를 대상으로 강수에 의한 오염 희석 규명을 시도하였다. 강수여과물에 대해 등온잔류자화(Isothermal remanent magnetization) 측정과 현미경 분석 및 정성적인 화학 성분 분석을 실시하였다. 비강수일에 포집한 먼지 시료와 황사발생일에 채취한 먼지 시료도 비교를 위해 실험에 사용하였다. 자화특성 실험과 현미경 관찰 결과를 바탕으로 판단하면, 강수에서 여과된 고체 시료에 존재하는 자성 물질은 자철석이다. 관찰된 자성 물질의 특이한 형태(구형/타원체형)와 탄소 함유를 고려하면, 인위적인 연소에 의해 형성된 자철석이라 해석된다. 강수에서 여과된 고체 시료의 등온잔류자화는 일반 먼지보다도 낮고 황사에 비해서는 현저히 낮은데, 이는 강수에 의해 발생하는 상당한 양의 자성물질 희석 효과라 판단된다.

To evaluate a potential wash-out effect of rainfalls, a preliminary environmental magnetic test was attempted. Measurement of isothermal remanent magnetization (IRM) and intensive microscopic observations were carried out on the solid particles extracted from the rainfalls collected for the past year (2009) in Daejeon, Korea. Dust particles collected from the rain-free (daily dust) or dustheavy days (during the Asian dust storm event) were also used as a comparison. IRMs were unanimously low for the solid particles extracted from the rainfalls, indicating an efficient wash-out effect of rainfalls as long as the magnetic concentration is concerned. Electron microscopy identified carbonbearing material, (carbon-coated) magnetite, and quartz. It is highly likely that the carbon-containing particles were produced by anthropogenic fossil fuel combustion.

키워드

참고문헌

  1. Bochirol, L. and Pauthenet, R. (1951) Animantation spontanee des ferrites. J. Physique, 12, 249-251. https://doi.org/10.1051/jphysrad:01951001203024900
  2. Griffin, J.J. and Goldberg, E.D. (1979) Morphologies and Origin of Elemental Carbon in the Environment. Science, 206, 563-565. https://doi.org/10.1126/science.206.4418.563
  3. Kim, W.N. (2007) Environmental application of rock magnetism: Development of a quantitative pollution monitoring tool. Ph.D. Thesis, Korea University, Seoul, Korea, 161p.
  4. Kim, W., Doh, S.J., Park, Y.H., and Yun, S.T. (2007) Two-year magnetic monitoring in conjunction with geochemical and electron microscopic data of roadside dust in Seoul, Korea. Atmos. Env., 41, 7627-7641. https://doi.org/10.1016/j.atmosenv.2007.05.050
  5. Kim, W., Doh, S., and Yu, Y. (2009) Anthropogenic contribution of magnetic particulates in urban roadside dust. Atmos. Env., 43, 3137-3144. https://doi.org/10.1016/j.atmosenv.2009.02.056
  6. Kim, W., Doh, S., Yu, Y., and Lee, M. (2008) Role of Chinese wind-blown dust in enhancing environmental pollution in Metropolitan Seoul. Env. Pollut., 153, 333-341. https://doi.org/10.1016/j.envpol.2007.08.014
  7. Lanci, L., Kent, D.V., Biscaye, P.E., and Bory, A. (2001) Isothermal remanent magnetization of Greenland ice: Preliminary results. Geophys. Res. Lett., 28, 1639-1642. https://doi.org/10.1029/2000GL012594
  8. Liu, Q., Banerjee, S.K., Jackson, M.J., Maher, B.A., Pan, Y., Zhu, R., Deng, C., and Chen, F. (2004) Grain sizes of susceptibility and anhysteretic remanent magnetization carriers in Chinese loess/paleosol sequences. J. Geophys. Res., 109, B03101, doi: 10.1029/2003 JB002747.
  9. Ma, C. J., Kasahara, M., Holler, R., and Kamiya, T. (2001) Characteristics of single particles sampled in Japan during the Asian dust-storm period. Atmos. Env., 35, 2707-2714. https://doi.org/10.1016/S1352-2310(00)00410-6
  10. MEK (Ministry of Environment of Korea), (2001) Annual report of ambient air quality in Korea, 2000 (in Korean). Ministry of Environment and National Institute of Environmental Research, Seoul, Korea.
  11. Rauch, S., Hemond, H.F., and Peucker-Ehrenbrink, B. (2004) Recent changes in platinum group element concentrations and osmium isotopic composition in sediments from an urban lake. Env. Sci. Tech., 38, 396-402. https://doi.org/10.1021/es0347686
  12. Robertson, D.J., Taylor, K.G., and Hoon, S.R. (2003) Geochemical and mineral magnetic characterisation of urban sediment particulates, Manchester, UK. Appl. Geochem., 18, 269-282. https://doi.org/10.1016/S0883-2927(02)00125-7
  13. Shilton, V.F., Booth, C.A., Smith, J.P., Giess, P., Mitchell, D.J., and Williams, C.D. (2005) Magnetic properties of urban street dust and their relationship with organic matter content in the West Midlands, UK. Atmos. Env., 39, 3651-3659. https://doi.org/10.1016/j.atmosenv.2005.03.005
  14. Shu, J., Dearing, J.A., Morse, A.P., Yu, L.Z., and Li, C.Y. (2000) Magnetic properties of daily sampled total suspended particulates in Shanghai. Env. Sci. Tech., 34, 2393-2400. https://doi.org/10.1021/es9910964
  15. Spassov, S., Egli, R., Heller, F., Nourgaliev, D.K., and Hannam, J. (2004) Magnetic quantification of urban pollution sources in atmospheric particulate matter. Geophys. J. Int., 159, 555-564. https://doi.org/10.1111/j.1365-246X.2004.02438.x
  16. Syono, Y. (1965) Magnetocrystalline anisotropy and magnetostriction of $Fe_{3}O_{4}$-$Fe_{2}TiO_{4}$ series with special application to rock magnetism. Jap. J. Geophys., 4, 71-143.
  17. Verwey, E.J.M. (1935), The crystal structure of y--Fe_{2}O_{3}$ and y-Al_{2}O_{3}$. Z. Krist., 91, 65-69.
  18. Whiteley, J.D. and Murray, F. (2005) Autocatalyst-derived platinum, palladium and rhodium (PGE) in infiltration basin and wetland sediments receiving urban runoff. Sci. Total Env., 341, 199-209. https://doi.org/10.1016/j.scitotenv.2004.09.030
  19. WHO (World Health Organization) (2003) Health aspects of air pollution with particulate matter, ozone and nitrogen dioxide. World Health, http://www.greenfacts.org/en.