Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Manganese(II) Ion-Selective Membrane Electrode Based on N-(2-picolinamido ethyl)-Picolinamide as Neutral Carrier

  • Aghaie, M. (Faculty of Chemistry, Islamic Azad University, North Tehran Branch) ;
  • Giahi, M. (Department of Chemistry, Faculty of Science, Islamic Azad University) ;
  • Zawari, M. (Department of Chemistry, Islamic Azad University, Science and Research Branch)
  • Received : 2010.12.04
  • Accepted : 2010.08.20
  • Published : 2010.10.20
Download PDF
⟨ Previous Next ⟩

Abstract

A new poly (vinyl chloride) (PVC) membrane electrode that is highly selective to $Mn^{+2}$ ions was prepared using N,N'-bis(2'-pyridinecarboxamide)-1,2-ethane ($bpenH_2$) as a suitable neutral carrier. This concentration range ($1.0{\times}10^{-5}$ to $1.0{\times}10^{-1}\;M$) with Nernstian slope of $29.3{\pm}0.5\;mV$ per decade. The detection limit and the response time of electrode were $8.0{\times}10^{-6}\;M$ and (${\leq}15\;s$) respectively. The membrane can be used for more than two months without observing any divergence. The electrodes exhibited excellent selectivity for $Mn^{+2}$ ion over other mono-, di- and trivalent cations. Selectivity coefficients were determined by the matched potential method (MPM). The electrode can be used in the pH range from 4.0 - 9.0. The isothermal coefficient of this electrode amounted to 0.00023 V/$^{\circ}C$. The stability constant (log $K_s$) of the $Mn^{+2}$ - $bpenH_2$ complex was determined at $25^{\circ}C$ by potentiometric titration in mixed aqueous solution. The proposed electrode was applied to the determination of $Mn^{+2}$ ions in real samples.

Keywords

References

  1. Srivastva, S. K.; Gupta, V. K.; Jain, S. Analyst 1995, 120, 495. https://doi.org/10.1039/an9952000495
  2. Mahajan, R. K.; Kumar, M.; Sharma, V.; Kaur, I. Analyst 2001, 126, 505. https://doi.org/10.1039/b008944n
  3. Mahajan, R. K.; Parkash, O. Talanta 2000, 52, 691. https://doi.org/10.1016/S0039-9140(00)00419-7
  4. Buhlmann, P.; Pretsch, E.; Bakker, E. Chem.Rev. 1998, 98, 1593. https://doi.org/10.1021/cr970113+
  5. Aghaie, H.; Giahi, M.; Monajjemi, M.; Arvand, M.; Nafissi, G. H.; Aghaie, M. Sens. Actuators B 2005, 107, 756. https://doi.org/10.1016/j.snb.2004.12.010
  6. Giahi, M.; Pournaghdy, M.; Rakhshaee, R. J. Anal. Chem. 2009, 64, 188.
  7. Assubaie, F. N.; Moody, G. J.; Thomas, G. J. Analyst 1989, 114, 1545. https://doi.org/10.1039/an9891401545
  8. Liu, Y.; Zhao, B. T.; Chen, L. X.; He, X. W. Microchemical J. 2000, 65, 75. https://doi.org/10.1016/S0026-265X(00)00033-3
  9. Giahi, M.; Arvand, M.; Mirzaei, M.; Bagherinia, M. A. Anal. Lett. 2009, 42, 870. https://doi.org/10.1080/00032710902722079
  10. Mahajan, R. K.; Kumar, M.; Sharma, V.; Kaur, I. Talanta 2002, 58, 545.
  11. US EPA (US Environmental Protection Agency). Integrated Risk Information System (IRIS) on Manganese, Environmental Criteria and Assessment Office, Office of Health and Environmental Assessment, Office of Research and Development, Cincinnati, OH, 1993.
  12. Maniasso, N.; Zagatto, E. A. G. Anal. Chim. Acta 1998, 366, 87. https://doi.org/10.1016/S0003-2670(97)00682-X
  13. Lal, U. S.; Chattopadhyaya, M. C.; Ghosh, K.; Dey, A. K. Indian Agriculturist (Spec. vol.) 1982, 139.
  14. Su, Y. Fenxi Huaxue 1983, 11, 905.
  15. Midgley, D.; Mulcahy, D. E. Talanta 1985, 32, 7. https://doi.org/10.1016/0039-9140(85)80004-7
  16. Agarwala, V.; Chattopadhyaya, M. C. Anal. Lett. 1989, 22, 1451. https://doi.org/10.1080/00032718908051611
  17. Singh, A. K.; Saxena, P.; Panwar, A. Sens. Actuators B 2005, 110, 377. https://doi.org/10.1016/j.snb.2005.02.022
  18. Barnes, D. J.; Chapman, R. L.; Vagg, R. S.; Watton, E. C. J. of Chemical & Engineering Data 1978, 23, 349. https://doi.org/10.1021/je60079a006
  19. Barnes D. J.; Chapman, R. L.; Stephens, F. S.; Vagg, R. S. Inorganic Chimica Acta 1981, 51, 155 . https://doi.org/10.1016/S0020-1693(00)88333-4
  20. Tavakkoli, N.; Shamsipur, M. Anal. Lett. 1996, 29, 2269. https://doi.org/10.1080/00032719608002251
  21. Matysik, S.; Matysik, F. M.; Mattusch, J.; Einicke, W. D. Electroanalysis 1998, 10, 98. https://doi.org/10.1002/(SICI)1521-4109(199802)10:2<98::AID-ELAN98>3.0.CO;2-N
  22. Bakker, E.; Pretsch, E.; Buhlmann, P. Anal. Chem. 2000, 72, 1127. https://doi.org/10.1021/ac991146n
  23. Bakker, E. Electroanalysis 1997, 9, 7. https://doi.org/10.1002/elan.1140090103
  24. Antropov, L. I. Theoretical Electrochemistry; Mir Publishers: Moscow, 1972; pp 180-183.
  25. Gutknecht, J.; Schneider, H. J. Stroka. Inorg. Chem. 1978, 17, 3326. https://doi.org/10.1021/ic50190a003
  26. Buck, R. P.; Lindner, E. Pure Appl. Chem. 1994, 66, 2527. https://doi.org/10.1351/pac199466122527

Cited by

  1. A Solid-Contact Ion Selective Electrode for Copper(II) Using a Succinimide Derivative as Ionophore vol.13, pp.4, 2013, https://doi.org/10.3390/s130404367
  2. A new kind of optical Mn(II) sensor with high selectivity: Melamine based poly(azomethine–urethane) vol.161, pp.17, 2010, https://doi.org/10.1016/j.synthmet.2011.06.029
  3. Novel coated wire potentiometric sensor for selective determination of Mn(II) ions in various authentic samples vol.18, pp.7, 2010, https://doi.org/10.1007/s13738-020-02135-2