Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Simultaneous Determination of Cd2+, Pb2+, Cu2+ and Hg2+ at a Carbon Paste Electrode Modified with Ionic Liquid-functionalized Ordered Mesoporous Silica

  • Zhang, Penghui (College of Sciences, Xi'an University of Architecture and Technology) ;
  • Dong, Sheying (College of Sciences, Xi'an University of Architecture and Technology) ;
  • Gu, Guangzhe (College of Sciences, Xi'an University of Architecture and Technology) ;
  • Huang, Tinglin (College of Environmental and Municipal Engineering, Xi'an University of Architecture and Technology)
  • Received : 2010.07.17
  • Accepted : 2010.09.01
  • Published : 2010.10.20
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Abstract

Ionic liquid-functionalized ordered mesoporous silica SBA-15 modified carbon paste electrode (CISPE) was fabricated and its electrochemical performance was investigated by cyclic voltammetry, electrochemical impedance spectra. The electrochemical behavior of $Cd^{2+}$, $Pb^{2+}$, $Cu^{2+}$ and $Hg^{2+}$ at CISPE was studied by differential pulse anodic stripping voltammetry (DPASV). Compared with carbon paste electrode, the stripping peak currents had a significant increase at CISPE. Under the optimized conditions, the detection limits were $8.0{\times}10^{-8}\;M$ ($Cd^{2+}$), $4.0{\times}10^{-8}\;M$ ($Pb^{2+}$), $6.0{\times}10^{-8}\;M$ ($Cu^{2+}$), $1.0{\times}10^{-8}\;M$ ($Hg^{2+}$), respectively. Furthermore, the present method was applied to the determination of $Cd^{2+}$, $Pb^{2+}$, $Cu^{2+}$ and $Hg^{2+}$ in water samples and people hair sample.

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References

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