Bulletin of the Korean Chemical Society

  • 제31권10호
  • /
  • Pages.2867-2872
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  • 2010
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Syntheses and Thermal Behaviors of Rb(FOX-7)·H2O and Cs(FOX-7)·H2O

  • Luo, Jinan (Department of Chemical Engineering, Northwest University) ;
  • Xu, Kangzhen (Department of Chemical Engineering, Northwest University) ;
  • Wang, Min (Department of Chemical Engineering, Northwest University) ;
  • Song, Jirong (Conservation Technology Department, the Palace Museum) ;
  • Ren, Xiaolei (Department of Chemical Engineering, Northwest University) ;
  • Chen, Yongshun (Department of Chemical Engineering, Northwest University) ;
  • Zhao, Fengqi (Xi'an Modern Chemistry Research Institute)
  • 투고 : 2010.05.17
  • 심사 : 2010.08.22
  • 발행 : 2010.10.20
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초록

Two new energetic organic alkali metal salts, 1,1-diamino-2,2-dinitroethylene rubidium salt [Rb(FOX-7)${\cdot}H_2O$] and 1,1-diamino-2,2-dinitroethylene cesium salt [Cs(FOX-7)${\cdot}H_2O$], were synthesized by reacting of 1,1-diamino-2,2-dinitroethylene (FOX-7) and rubidium chloride or cesium chloride in alkali methanol aqueous solution, respectively. The thermal behaviors of Rb(FOX-7)${\cdot}H_2O$ and Cs(FOX-7)${\cdot}H_2O$ were studied with DSC and TG methods. The critical temperatures of thermal explosion of the two compounds are 216.22 and $223.73^{\circ}C$, respectively. Specific heat capacities of the two compounds were determined with a micro-DSC method, and the molar heat capacities are 217.46 and $199.47\;J\;mol^{-1}\;K^{-1}$ at 298.15 K, respectively. The adiabatic times-to-explosion were also calculated to be a certain value of 5.81 - 6.36 s for Rb(FOX-7)${\cdot}H_2O$, and 9.92 - 10.54 s for Cs(FOX-7)${\cdot}H_2O$. After FOX-7 becoming alkali metal salts, thermal decomposition temperatures of the compounds heighten with the rise of element period, but thermal decomposition processes become intense.

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