Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Characterization of New Tetraaza Macrocycles Bearing Two or Four N-Methoxyethyl Pendant Arms and Their Copper(II) and/or Nickel(II) Complexes

  • Received : 2010.05.26
  • Accepted : 2010.07.22
  • Published : 2010.09.20
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Abstract

This work shows that both L2 and L3 bearing two and four N-$(CH_2)_2OCH_3$ groups, respectively, can be prepared selectively by the reaction of $L^1$ with 1-bromo-2-methoxyethane. The di-N-substituted macrocycle $L^2$ readily forms its copper(II) and nickel(II) complexes. The N-$(CH_2)_2OCH_3$ groups in $[CuL^2]^{2+}$ are coordinated to the metal ion, whereas those in $[NiL^2]^{2+}$ are not involved in coordination. Interestingly, $L^3$ reacts with $Cu^{2+}$ ion to form $[Cu(HL^3)]^{3+}$, in which one tertiary amino group is not involved in coordination.

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References

  1. Viola-Villegas, N.; Doyle, R. P. Coord. Chem. Rev. 2009, 253, 1906. https://doi.org/10.1016/j.ccr.2009.03.013
  2. Costamagna, J.; Ferraudi, G.; Matsuhiro, B.; Vampus-Vallette, M.; Canales, J.; Villagran, M.; Vargas, J.; Aguirre, M. J. Coord. Chem. Rev. 2000, 196, 125. https://doi.org/10.1016/S0010-8545(99)00165-4
  3. Lukes, I.; Kotek, J.; Vojtisek, P.; Hermann, P. Coord. Chem. Rev. 2001, 216-217, 287. https://doi.org/10.1016/S0010-8545(01)00336-8
  4. Organo, V. G.; Filatov, A. S.; Quartararo, J. S.; Friedman, Z. M.; Rybak-Akimova, E. V. Inorg. Chem. 2009, 48, 8458.
  5. Silversides, J. D.; Allan, C. C.; Archibald, S. J. Dalton Trans. 2007, 971.
  6. Kang, S.-G.; Nam, K.; Jeong, J. H. Inorg. Chim. Acta 2009, 362, 1083. https://doi.org/10.1016/j.ica.2008.05.016
  7. Kang, S.-G.; Kim, H.; Kim, N.; Jeong, J. H. Bull. Korean Chem. Soc. 2009, 30, 3101. https://doi.org/10.5012/bkcs.2009.30.12.3101
  8. Siegfried, L.; Comparone, A.; Neuburger, M.; Kaden, T. A. Dalton Trans. 2005, 30.
  9. Kang, S.-G.; Kim, M.-S.; Choi, J.-S.; Whang, D.; Kim, K. J. Chem. Soc., Dalton Trans. 1995, 363.
  10. Kang, S.-G.; Kweon, J. K.; Lee, Y. H.; Kim, J.-S.; Lee, U. Bull. Korean Chem. Soc. 2007, 28, 489. https://doi.org/10.5012/bkcs.2007.28.3.489
  11. Kang, S.-G.; Kweon, J. K.; Jeong, G. R.; Lee, U. Bull. Korean Chem. Soc. 2008, 29, 1905. https://doi.org/10.5012/bkcs.2008.29.10.1905
  12. Suh, M. P.; Choi, J.; Kang, S.-G.; Shin, W. Inorg. Chem. 1989, 28, 1763. https://doi.org/10.1021/ic00308a034
  13. Suh, M. P.; Lee, J.; Han, M. Y.; Yoon, T. S. Inorg. Chem. 1997, 36, 5651. https://doi.org/10.1021/ic970020a
  14. Kang, S.-G.; Kweon, J. K.; Jung, S.-K. Bull. Korean Chem. Soc. 1991, 12, 483.
  15. Sheldrick, G. M. SHELEXL-97, University of Goettingen, Goettingen, Germany, 1997.
  16. Kang, S.-G.; Kim, M.-S.; Choi, J.-S. Cho, M. N. Polyhedron 1995, 14, 781. https://doi.org/10.1016/0277-5387(94)00299-T
  17. Kang, S.-G.; Choi, J.-S.; Nam, K.; Chun, H; Kim, K. Inorg. Chim. Acta 2004, 357, 2783. https://doi.org/10.1016/j.ica.2004.02.034
  18. Kang, S.-G.; Ryu, K. Bull. Korean Chem. Soc. 2000, 21, 535.
  19. Kang, S.-G.; Kim, M.-S.; Whang, D.; Kim, K. Inorg. Chim. Acta 1998, 279, 238. https://doi.org/10.1016/S0020-1693(98)00123-6
  20. Styka, M. C.; Smierciak, R. C.; Blinn, E. L.; DeSimone, R. E.; Passariello, J. V. Inorg. Chem. 1978, 17, 82. https://doi.org/10.1021/ic50179a018
  21. Duggan, M.; Ray, N.; Hathaway, B.; Tomlinson, G.; Brint, P.; Pelin, K. J. Chem. Soc., Dalton Trans. 1980, 1342.
  22. Kang, S.-G.; Kim, N.; Jeong, J. Inorg. Chim. Acta 2008, 361, 349. https://doi.org/10.1016/j.ica.2007.05.057
  23. McLachlan, G. A.; Fallon, G. D.; Martin, R. L.; Spiccia, L. Inorg. Chem. 1995, 34, 254. https://doi.org/10.1021/ic00105a041

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