Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A Green Protocol for Catalytic Conversion of Epoxides to 1,2-Diacetoxy Esters with Phosphomolybdic Acid Alone or Its Supported on Silica Gel

  • Received : 2010.06.28
  • Accepted : 2010.08.04
  • Published : 2010.09.20
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Abstract

Catalytic conversion of structurally different epoxides to the corresponding 1,2-diacetoxy esters was carried out readily with phosphomolybdic acid alone or its supported on $SiO_2$. The reactions were carried out under solvolytic or solvent free conditions within 5-15 min at room temperature. The product 1,2-diacetates were obtained in high to excellent yields. Supporting of phosphomolybdic acid on $SiO_2$ showed the better catalytic activity than $Al_2O_3$. Conversion of optically pure R-(+)-styrene oxide to S-(+)-1,2-diacetoxy-1-phenylethane was carried with phosphomolybdic acid in high yield and stereospecificity.

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