Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Two Novel 3-D Zinc Compounds with Mixture Ligands of H3BTB and 4,4'-Bipy: Crystal Structures, Blue Fluorescence and Single Point Energy Calculation

  • Zhang, Xiu-Cheng (College of Science, Northeast Forestry University) ;
  • Xu, Ling (Department of Chemistry, Sungkyunkwan University) ;
  • Liu, Wen-Guang (College of Science, Northeast Forestry University) ;
  • Liu, Bing (Department of Chemistry, University of Aveiro, CICECO, Campus Universitario de Santiago)
  • Received : 2010.05.27
  • Accepted : 2010.07.19
  • Published : 2010.09.20
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Abstract

Two 3-D zinc framework compounds, $[Zn_6(BTB)_4(4,4'-bipy)_4(H_2O)_4]{\cdot}9H_2O$ (1) and $[Zn_3(BTB)_2(4,4'-bipy)_2(H_2O)_2]{\cdot}5H_2O$ (2) ($H_3BTB$ = 1,2,3-benzenetricarboxylic acid, 4,4'-bipy = 4,4'-bipyridine), are obtained from the diffusion method and hydrothermal reaction respectively. Though 1 and 2 has the same coordination geometries of zinc atoms and coordination mode of $BTB^{3-}$, their 2-D layers are different: mirror symmetric layers in 1; parallel ones in 2, further connecting by 4,4'-bipy into 3-D frameworks. The hydrothermal reaction of 2 results in a more stable 3-D framework than the one in 1, which is supported by the single point energy calculations. 1 and 2 show similar blue fluorescence at 417 nm, which can be assigned to LMCT.

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References

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