Journal of the Korean Electrochemical Society (전기화학회지)

The Korean Electrochemical Society (한국전기화학회)
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Physical Properties of Lithium Co-polyelectrolyte Based on Imidazolium and Ammonium-type Ionic Liquids

  • Cha, E.H. (College of liberal arts & Science, Hoseo Univ.) ;
  • Lim, S.A. (School of AIBN, Queensland University) ;
  • Kim, D.W. (Dept of chemical Engineering HanYang Univ.) ;
  • Lee, J.K. (College of liberal arts & Science, Hoseo Univ.) ;
  • Park, J.H. (Department of Chemistry, Korea University)
  • Received : 2010.07.30
  • Accepted : 2010.08.17
  • Published : 2010.08.28
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Abstract

Lithium co-polyelectrolyte-ionic liquid systems, using poly (lithium 2-acrylamido-2-methyl propanesulfonate; PAMPSLi) and polyvinyl formamid (PVF) were prepared and their electrochemical and physical properties were measured. The conductivity of co-polymer systems, PAMPSLi/PVF/N, N-dimethyl-N-propyl-N-butylammonium tricyanomethanide (PAMPSLi/PVF/$N_{1134}$TCM) and PAMPSLi/PVF/N, N-dimethyl-N-propyl-N-butylammonium dicyanamide (PAMPSLi/PVF/$N_{1134}$DCA) exhibited low viscosity ($N_{1134}$TCM:$N_{1134}$DCA 28.6cP, 28.7cP) and higher conductivity ($2.48{\times}10^{-3}Scm^{-1}$, $2.2{\times}10^{-3}Scm^{-1}$) than homopolymer system. The ionic conductivity PAMPSLi/PVF/1-ethyl-3-methyl imidazolium dicyanamide (PAMPSLi/PVF/emImDCA) exhibited $1.54{\times}10^{-3}Scm^{-1}$ and low viscosity (emImDCA: 28.09cP). High flexibility of imidazolium cation and dissociation of lithium cation from the co-polymer chains were affected by high conductivity and low viscosity.

Keywords

References

  1. Wataru Ogihara, Satiko Washiro, Hiromitsu nakajima, Hiroyuki Ohno, Electro- chimica Acta, ‘Effect of cation structure on the electrochemical and thermal properties of ion conductive polymers obtained from polymerizable ionic liquids’ 51, 2614 (2006).
  2. Qing Dai, David B.Menzies, D.R Macfarlane, Stuart R, Batten, Stewart Forsyth, Leone spiccia, Yi-Bing Cheng, Maria Forsyth, C.R. Chimie,’ Dye-sensitized nanocrystalline solar cells incorporating ethylmethylimidazolium-based ionic liquid electolytes’ 9, 617 (2006). https://doi.org/10.1016/j.crci.2005.03.028
  3. Hiroyuki Ohno, Masahiro Yoshizawa, Wataru Ogihara, Electrochimica Acta, ‘Develoment of new class of ion conductive polymers based on ionic liquids’ 50, 255 (2004). https://doi.org/10.1016/j.electacta.2004.01.091
  4. Stewart A. Forsyth, Jennifer M. Pringle, and Douglas R. MacFarlane, Aust, J. Chem., ‘Ionic Liquids based on Imidazolium and Pyrrolidinium Salts of the tricyanomethanide anion’ 57, 113 (2004). https://doi.org/10.1071/CH03231
  5. A. B. McEwen, H. L. Ngo, K. LeCompte and J. L. Goldman, J. Electrochem Soc.’ Electrochemical Properties of imidazolium Salt Electrolyte for Electrochemical Capacitor Applications’ 146, 1687 (1999). https://doi.org/10.1149/1.1391827
  6. Kaori Ito, Naoko Nishina, hiroyuki Ohno, Electrochimica Acta, ’Enhanced ion conduction in imidazolium-type molten salts’ 45, 1295 (2000). https://doi.org/10.1016/S0013-4686(99)00335-7
  7. Thomas E. Sutto, Hugh C. De long, and Paul C. Trulove Z. Naturforch.’ Physical Properties of Substituted Imidazolium Based Ionic Liquids Gel Electrolytes’ 57a, 839 (2002).
  8. R. T. Carlin, J. Fuller, W. K. Kuhn, M. J. Lysaght, and P. C. Trulove, J.Appl. Electrochem,’Electrochemistry of roomtemperature chloroaluminate molten salts at graphitic and nongraphitic electrode’ 26, 1147 (1996).
  9. D. R. Macfarlane, S. A. Forsyth, J. Golding and B. Deacon, Greenchemistry, ‘Ionic liquids based on imidazolium, ammonium and pyrrolidinium salts of the dicyanamide anion’ 4, 444 (2002).
  10. M. Forsyth, J. Sun, F. Zhou, D. R. MacFarlane, Electrochimica Acta, ‘Enhancement of ion dissociation in polyelectrolyte gels’ 48, 2129 (2003). https://doi.org/10.1016/S0013-4686(03)00195-6
  11. E. H. Cha, S. A. Lim, D. W. Kim, N. S. Choi, J. Korean Electrochemical Society, ‘Electrochemical Characterization of lithium polyelectrolyte based on ionic Liquid’ 12, No3, 271 (2009). https://doi.org/10.5229/JKES.2009.12.3.271
  12. E. H. Cha, S. A. Lim, J. H. Park, D. W. Kim. D. R. Macfarlane, J. Power Sources, ‘Ionic conductivity studies of gel polyelectrolyte based on ionic liquid’ 178, 779 (2008). https://doi.org/10.1016/j.jpowsour.2007.10.033

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