Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Wire-like Bundle Arrays of Copper Hydroxide Prepared by the Electrochemical Anodization of Cu Foil

  • La, Duc-Duong (Department of Applied Chemistry, and Graduate School of Bio-Nano Engineering, Hanyang University) ;
  • Park, Sung-Yeol (Department of Applied Chemistry, and Graduate School of Bio-Nano Engineering, Hanyang University) ;
  • Choi, Young-Wook (Process Materials Research Institute, Cheil Industries Inc.) ;
  • Kim, Yong-Shin (Department of Applied Chemistry, and Graduate School of Bio-Nano Engineering, Hanyang University)
  • Received : 2009.08.05
  • Accepted : 2010.06.23
  • Published : 2010.08.20
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Abstract

Nanostructured copper compounds were grown by electrochemical anodization of copper foil in aqueous NaOH under varying conditions including electrolyte concentration, reaction temperature, current density, and reaction time. Their morphology and atomic composition were investigated by using SEM, TEM, XRD, EDS and XPS. At the conditions ([NaOH] = 1 M, $20^{\circ}C$, $2\;mA\;cm^{-2}$), wire-like orthorhombic $Cu(OH)_2$ nanobundles with an average width of 100 - 300 nm and length of $10\;{\mu}m$ were synthesized with the preferential [100] growth direction. Furthermore, when the concentration decreased to 0.5 M NaOH, the 1D nanobundle structure became narrower and longer without any change in compositions or crystalline structure. Side reaction pathways appeared to compete with the 1D nanostructure formation channels: the formation of CuO nanoleaves at $50^{\circ}C$ via the sequential dehydration of $Cu(OH)_2$, CuO/$Cu_2O$ aggregates in 4 M NaOH, and $Cu_2O$ nanoparticles and CuO nanosheets at lower current density.

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References

  1. Cao, G. Nanostructures & nanomaterials: Synthesis, Properties & Application; Imperial college press: London, 2004; pp 110-173.
  2. Ozin, G. A.; Arsenault, A. C. Nanochemistry: A Chemical Approach to Nanomaterials; RSC publishing: Cambridge, 2005; pp 167-265.
  3. Ajayan, P. M.; Stephan, O.; Redlich, Ph.; Colliex, C. Nature 1995,375, 564. https://doi.org/10.1038/375564a0
  4. Ha, W.; Fan, S.; Li, Q.; Hu, Y. Science 1997, 277, 1287. https://doi.org/10.1126/science.277.5330.1287
  5. Xia, Y.; Rogers, J. A.; Paul, K. E.; Whitesides, G. M. Chem. Rev.1999, 99, 1823. https://doi.org/10.1021/cr980002q
  6. Xia, Y.; Yang, P.; Sun, Y.; Wu, Y.; Brian, M.; Byron, G.; Yin, Y.; Kim, Y.; Yan, H. Adv. Mater. 2003, 15, 353. https://doi.org/10.1002/adma.200390087
  7. Wen, X.; Zhang, W.; Yang, S. Nano Lett. 2002, 2, 1397. https://doi.org/10.1021/nl025848v
  8. Zhang, W.;Wen, X.; Yang, S.; Berta, Y.; Wang, Z. L. Adv. Mater.2003, 15, 822. https://doi.org/10.1002/adma.200304840
  9. Zhang, W.; Wen, X.; Yang, S. Inorg. Chem. 2003, 42, 5005. https://doi.org/10.1021/ic0344214
  10. Wen, X.; Zhang, W.; Yang, S. Langmuir 2003, 19, 5898. https://doi.org/10.1021/la0342870
  11. Wen, X.; Xie, Y.; Choi, C. L.; Wan, K. C.; Li. X.-Y.; Yang, S. Langmuir 2005, 21, 4729. https://doi.org/10.1021/la050038v
  12. Shoesmith, D. W.; Rummery, T. E.; Owen, D.; Lee, W. J. Electrochem. Soc. 1976, 123, 790. https://doi.org/10.1149/1.2132934
  13. Wu, X.; Bai, H.; Zhang, J.; Chen, F.; Shi, G. J. Phys. Chem. B2005, 109, 22836. https://doi.org/10.1021/jp054350p
  14. Pan, Q.; Jin, H.; Wang, H. Nanotechnology 2007, 18, 355605. https://doi.org/10.1088/0957-4484/18/35/355605
  15. Wu, X.; Shi, G. J. Phys. Chem. B 2006, 110, 11247. https://doi.org/10.1021/jp056969x
  16. Chen, X.; Kong, L.; Dong, D.; Yang, G.; Yu, L.; Chen, J.; Zhang,P. Appl. Surf. Sci. 2009, 255, 4015. https://doi.org/10.1016/j.apsusc.2008.10.104
  17. Pan, Q.; Wang, M.; Wang, H. Appl. Surf. Sci. 2008, 254, 6002. https://doi.org/10.1016/j.apsusc.2008.03.034
  18. Wang, S.; Song, Y.; Jiang, L. Nanotechnology 2007, 18, 015103. https://doi.org/10.1088/0957-4484/18/1/015103
  19. Hou, H.; Xie, Y.; Li, Q. Cryst. Growth Des. 2005, 5, 201. https://doi.org/10.1021/cg049972z
  20. Xu, H.; Wang, W.; Zhu, W.; Zhou, L.; Ruan, M. Cryst. Growth Des. 2007, 7, 2720. https://doi.org/10.1021/cg060727k
  21. Reitz, J. B.; Solomon, E. I. J. Am. Chem. Soc. 1998, 120, 11467. https://doi.org/10.1021/ja981579s
  22. Wang, H.; Pan, Q.; Zhao, J.; Yin, G.; Zuo, P. J. Power Sources 2007, 167, 206. https://doi.org/10.1016/j.jpowsour.2007.02.008
  23. Hoque, E.; DeRose, J. A.; Houriet, R.; Hoffmann, P.; Mathieu, H. J. Chem. Mater. 2007, 19, 798. https://doi.org/10.1021/cm062318h
  24. http://www.lasurface.com.
  25. Vere, A. W. In Crystal Growth: Principles and Progress; Dobson, P. J., Ed.; Plenum Press: New York, 1987; p 17.
  26. Singh, D. P.; Neti, N. R.; Sinha, A. S. K.; Srivastava, O. N. J. Phys. Chem. C 2007, 111, 1638. https://doi.org/10.1021/jp0657179
  27. Becerra, J. G.; Salvarezza, R. C.; Arvia, A. J. Electrochimica Acta1988, 33, 613. https://doi.org/10.1016/0013-4686(88)80059-8
  28. Shoesmith, D. W.; Rummery, T. E.; Owen, D.; Lee, W. J. Electrochem. Soc. 1976, 123, 790. https://doi.org/10.1149/1.2132934
  29. Bouillon, F.; Piron, J.; Stevens, J. Bull. Soc. Chim. Belges 1958,67, 643. https://doi.org/10.1002/bscb.19580671102

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