Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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The Synthesis and Characterization of Some Novel Thioethers: Thio-Subsituted [3]Cumulenes, -1-Buten-3-ynes and Buta-1,3-dienes

  • Ibis, Cemil (Istanbul University, Faculty of Engineering, Department of Chemistry) ;
  • Sahin, Aysecik (Istanbul University, Faculty of Engineering, Department of Chemistry)
  • Received : 2010.05.13
  • Accepted : 2010.06.17
  • Published : 2010.08.20
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Abstract

In this study, some novel thiosubstituted butenyne (3a-d, 7b, 15b), butadiene (4a-b, 4d, 5a, 5c, 6b, 8e, 9c, 10b, 16b, 18e) and [3]cumulene (11a-b with isomer 3a-b, 12a with isomer 13a, 14b, 17e) compounds were synthesized from the reaction of 2H-pentachloro-1,3-butadiene with thiols. The new compounds were characterized by elemental analysis, mass spectrometry, UV-vis, IR, 1H NMR, NMR ($^{13}C$ or APT) spectroscopy.

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References

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