Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Formation and Related-Behavior of Micro-bowl Morphology Consisting of Ionic Palladium(II) Complexes

  • Kim, Cho-Rong (Department of Chemistry, Pusan National University) ;
  • Kim, Chi-Won (Department of Chemistry, Pusan National University) ;
  • Noh, Tae-Hwan (Department of Chemistry, Pusan National University) ;
  • Lee, Young-A (Department of Chemistry, Chonbuk National University) ;
  • Hong, Jong-Ki (College of Pharmacy, Kyung Hee University) ;
  • Jung, Ok-Sang (Department of Chemistry, Pusan National University)
  • Received : 2010.03.30
  • Accepted : 2010.06.12
  • Published : 2010.08.20
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Abstract

Reaction of [(bpy)Pd]$(PF_6)_2$ (bpy = 2,2'-bipyridine) with racemic bis(isonicotinoyl)-1,1'-bi-2-naphtholate (L) in acetone, and followed by addition of chloroform and solvent evaporation allows to form amorphous micro-bowl morphology consisting of $[(bpy)PdL]_2(PF_6)_4$ without any template or additive. In contrast, the reaction and recrystallization in acetone for 1 week produce parallel-piped single crystals consisting of $[(bpy)_3Pd_3({\mu}_3-HPO_4)_2](PF_6)_2$. The formations of micro-bowl and parallel-piped single crystal morphologies appear to be primarily associated with the kinetic and thermodynamic control, respectively. The formation of micro-bowls may be attributed to eruption of organic solvents. Cosolvent effects and chemical properties on the formation of micro-bowl morphology have been observed.

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