Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Delicate Difference in Coordinating Nature between Copper(II) and Nickel(II) Ions. Structural Properties of Copper(II) and Nickel(II) Nitrate Containing 1,2-Bis(dimethyl-3-pyridylsilyl)ethane

  • Kim, Shin-A (Department of Chemistry, Pusan National University) ;
  • Kim, Chi-Won (Department of Chemistry, Pusan National University) ;
  • Noh, Tae-Hwan (Department of Chemistry, Pusan National University) ;
  • Lee, Young-A (Department of Chemistry, Chonbuk National University) ;
  • Jung, Ok-Sang (Department of Chemistry, Pusan National University)
  • Received : 2010.03.16
  • Accepted : 2010.06.04
  • Published : 2010.08.20
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Abstract

Studies on the molecular construction and structures of $M(NO_3)_2$ (M = Cu(II), Ni(II)) complexes with 1,2-bis(dimethyl-3-pyridylsilyl)ethane (L) have been carried out. Formation of each molecular skeleton appears to be primarily associated with a suitable combination of bidentate N-donors of L and coordinating nature of octahedral metal(II) ions: [$Cu(NO_3)_2(L)_2$] yields a 2-dimensional sheet structure consisting of 44-membered $Cu_4L_4$ skeleton whereas $[Ni(L)_2(H_2O)_2](NO_3)_2$ produces an interpenetrated 3-dimensional structure consisting of 66-membered cyclohexanoid ($M_6L_6$) skeleton. The Cu(II) ion prefers nitrate whereas the Ni(II) ion prefers water molecules as the fifth and the sixth ligands.

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