수치모사를 이용한 CDI Unit Cell 내부의 유로성능 평가

COMPUTATIONAL STUDY FOR PERFORMANCE EVALUATION OF FLOW CHANNELS INSIDE CDI UNIT CELL

  • 손덕영 (아주대학교 대학원 기계공학과) ;
  • 최윤호 (아주대학교 기계공학부) ;
  • 박대욱 (삼성전자 DMC 연구소) ;
  • 정충효 (삼성전자 종합기술원)
  • 투고 : 2009.12.14
  • 심사 : 2010.02.05
  • 발행 : 2010.03.31

초록

In the present study, computations for flow fields inside the CDI unit cells with electrodes and spacers have been made to evaluate their performance. Three types of unit cells that include a planar type, a serpentine channel type, and a spiral wound type were considered and their flow characteristics were compared. From the computational results, it is found that the serpentine channel type has a large flow resistance and can not guarantee the outflow flux for industrial applications. On the other hand, the planar type can sustain a large enough outflow flux but it's efficiency is low for the electrode-use because of the non-uniform velocity distribution inside the cell and dead zones in every corner. Finally, The spiral wound type has not only a large outflow flux as much as the planar type has, but also a high efficiency for the electrode-use because of uniform velocity distribution. From this comparison, we can expect that the spiral wound type of CDI unit cell would have a high performance deionization capability.

키워드

참고문헌

  1. 1996, Farmer, J.C., Fix, D.V., Mack, G.V., Pekala, R.W. and Poco, J.F., "Capacitive Deionization of $NH_4ClO_4$Solutions with Carbon Aerogel Electrodes," J. Apple. Electrochemistry, Vol.26-10, pp.1007-1018.
  2. 1997, Farmer, J.C., Bahowick, S.M., Harrar, J.E., Fix, D.V., Martinelli, R.E., Vu, A.K. and Caroll, K.L., "Electrosorption of Chromium Ions on Carbon Aerogel Electrodes as a Means of Remediating Ground Water," Energy and Fuels, Vol.11-2, pp.337-347.
  3. 1996, Farmer, J.C. and Joseph, C., "Capacitive Deionization of NaCl and NaNO3 Solutions with Carbon Aerogel Electrodes," J. Apple. Electrochemistry, Vol.143-1, pp.159-169.
  4. 2004, 손정식, "전기이중층 모델을 이용한 이온의 전기흡착 거동 해석," 석사학위논문, 전남 대학교, 전남.
  5. 2005, 전상훈, "탄소나노물질을 이용한 CDI 공정 모사," 석사학위논문, 아주 대학교, 수원.