DOI QR코드

DOI QR Code

$TiO_2$/Acrylate 코어-셀 합성에서 계면활성제의 영향에 관한 연구

A Study on the Effect of Surfactant in Synthesizing Titanium Dioxide/Acrylate Core-Shell Polymer

  • 김덕술 (동명대학교 의용공학과) ;
  • 박근호 (창원대학교 화공시스템공학과)
  • Kim, Duck-Sool (Dept. of Biomedical Engineering, Tongmyong University) ;
  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University)
  • 투고 : 2010.02.13
  • 심사 : 2010.03.22
  • 발행 : 2010.03.30

초록

Titanium dioxide particles are used as photocatalysts, sensors, adsorbents and catalyst. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 0.5~2.0 wt% EU-S133D, Titanium dioxide / Acrylate core-shell polymerization was carried out on the surface of Titanium dioxide particle without forming the new Titanium dioxide particle during acrylate shell polymerized in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

키워드

참고문헌

  1. Zheng Y, Shi E, Chen Z, Li W, Hu X, Influence of solution concentration on the hydrothermal preparation of titania crystallites, J. Mater. Chem., 11, 1547, (2001). https://doi.org/10.1039/b009203g
  2. L. H. Lee and Y. S. Yang, Influence of the Molar Ratio of Cl-total:Ti+4 on the Crystalline Structure in Preparation of Ti02 from Aqueous TiOCl2 Solution by Homogeneous Precipitation Method, J. Kor. Jnd. Eng. Chem., 16, 785 (2005).
  3. J. M. Henmann, H. Tahiri, Y. Ait-Ichou, G. Lassaletta. AR. Gonzalez-Elipe, and A. Fernandez', Characterization and Photocatalytic Activity In Aqueous Medium 이 $TiO_{2}$ and $AgTiO_{2}$ Coatings on Quartz, Appl Catal B, 13, 219 (1997). https://doi.org/10.1016/S0926-3373(96)00107-5
  4. S.-S. Choi, S. G Lee, C. w. 100. S. S. Im, and S. H. Kim, Formation of Interfiber Bonding in Etectrospun Poly(etherimide) Nanofiber Web, J. Mater Sci, 39, 1511 (2004). https://doi.org/10.1023/B:JMSC.0000013931.84760.b0
  5. Jiang Zhao, Changwen Jia, Huigao Duan, Hui Li, Erqing Xie, Structural properties and photoluminescence of $TiO_{2}$ nanofibers were fabricated by electro - spinning, Journal of Alloys and Compounds, 461, 447 (2008). https://doi.org/10.1016/j.jallcom.2007.07.018
  6. Yanhuai Ding, Ping Zhang, Zhilin Long, Yong Jiang , Fu Xu , Jianguang Lei, Fabrication and photocatalytic property of $TiO_{2}$ nanofibers, J. Sol-Gel Sci. technol, 46, 1769 (2008).
  7. Tianzhu Zhang. Liqin Ge, Xing, Wang, Zhongze Gu, Hollow $TiO_{2}$ containing multilayer nanofibers with enhanced photocatalytic activity, Polymer, 49, 2898 (2008). https://doi.org/10.1016/j.polymer.2008.04.035
  8. A Pottier, C. Chaneac, E. Trone, L. Mazerolles, and j. P.Jolivet, Synthesis of brookite $TiO_{2}$ nanopaticles by thermolysis of TiC4 in strongly acide aqueous medi a, J. Materrial Chemistry, 11, 1116 (2001). https://doi.org/10.1039/b100435m
  9. H. D. Nam, B. H. Lee, S. J. Kim, C. H. Jung, J. H. Lee, and S. Park, Preparation of ultrafine crystalline $TiO_{2}$ powders from aqueous TiC4 solution by precipitation, Japanese J. Applied Physics, 37, 4003 (1998).
  10. J. Yang, S. Mei, and j. M. F. Ferreira, Hyd.rothermal synthesis of nanosized titania powders: Influence of peptizing agent on the crystalline phase and phase transitions, J. American Ceramic Sociiet y, 83(6), 1361 (2000). https://doi.org/10.1111/j.1151-2916.2000.tb01394.x
  11. L. Gao and Q. Zhang, The promoting effect of sulfate ions on the nucleation of TiOz(anatase) nanocrystals, Materials Transactions, 42(8), 1676 (2001). https://doi.org/10.2320/matertrans.42.1676
  12. X. Z. Aing, Z. Z. Qi and Y. Z. He, Effect of Hydrolysis Water on the Preparation of Nano-crtstalline Titania Powder via A Sol-Gel Process, J. Met. Sci. Lett, 14, 21 (1995). https://doi.org/10.1007/BF02565273
  13. K. G. Lee and K. H. Park, Preparation and Physical Properties of Poly(Styrene/Acrylate) Core-Shell Latex Particles, J. Kor. Oil Chem. Soc., 20(2), 27 (2003).
  14. J. S. Yoon and H. J. Jin, Emlsion Polymerization, Polymer Sci. and Tech 7, 412 (1996).
  15. J. B. Kwon, N. W. Lee, and S. D. Seul, A Consideration on Thermal Stability of the PV Ac Latex Adhesive, J. Kor. Soc. of Scfety, 18(3), 81 (2003).
  16. S. D. Seul, S. R. Lee, and N. W. Lee, A Development of Nontoxic Composite Latex Using $CaCO_{3}$/ PEMA, J. Kor. Soc. of Safety, 17(4), 133 (2002).
  17. Y. S. Choi, Y. K. Kim, and I. J. Chung, Poly (methyl methacrylate-co-styrene)/ Silicate Nanocomposites Synthesized by Multistep Emulsion Polymerization, Macromolecular Research Formerly Korea Polymer J., 11(6), 418 (2003).