Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Optimization of Emulsion Polymerization for Submicron-Sized Polymer Colloids towards Tunable Synthetic Opals

  • Received : 2009.09.14
  • Accepted : 2010.05.04
  • Published : 2010.07.20
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Abstract

Submicron-sized polymeric colloidal particles can self assemble into 3-dimensional (3D) opal structure which is a useful template for photonic crystal. Narrowly dispersed polymer microspheres can be synthesized by emulsion polymerization in water using water-soluble radical initiator. In this report, we demonstrate a facile and reproducible emulsion polymerization method to prepare various polymeric microspheres within 200 - 400 nm size ranges which can be utilized as colloidal photonic crystal template. By controlling the amount of monomer and surfactant, monodisperse polymer colloids of polystyrene (PS) and acrylates with various sizes were successfully prepared without complicated synthetic procedures. Such polymer colloids self-assembled into 3D opal structure exhibiting bright colors by reflection of visible light. The colloidal particles and the resulting opal structures were rigorously characterized, and the wavelength of the structural color from the colloidal crystal was confirmed to have quantitative relationship with the size of constituting colloidal particles as predicted by Bragg equation. The tunability of the structural color was achieved not only by varying the particle size but also by infiltration of the colloidal crystal with liquids having different refractive indices.

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References

  1. Joannopoulos, J. D.; Meade, R. D.; Winn, J. N. Photonic Crystals:Molding the Flow of Light; Princeton University Press: Princeton,1995.
  2. John, S. Phys. Rev. Lett. 1987, 58, 2486. https://doi.org/10.1103/PhysRevLett.58.2486
  3. Noda, S.; Chutinan, A.; Imada, M. Nature 2000, 407, 608. https://doi.org/10.1038/35036532
  4. Shkunov, M. N.; DeLong, M. C.; Raikh, M. E.; Vardeny, Z. V.;Zakhidov, A. A.; Barughman, R. H. Synthetic Matals 2001, 116,485. https://doi.org/10.1016/S0379-6779(00)00420-3
  5. Braun, P. V.; Rinne, S. A.; Garcia-Santamaria, F. Adv. Mater. 2006,18, 2665. https://doi.org/10.1002/adma.200600769
  6. Lee, W.; Pruzinsky, S. A.; Braun, P. V. Adv. Mater. 2002, 14, 271. https://doi.org/10.1002/1521-4095(20020219)14:4<271::AID-ADMA271>3.0.CO;2-Y
  7. Pruzinsky, S. A.; Braun, P. V. Adv. Func. Mater. 2005, 15, 1995. https://doi.org/10.1002/adfm.200500345
  8. Lee, K.; Asher, S. A. J. Am. Chem. Soc. 2000, 122, 9534. https://doi.org/10.1021/ja002017n
  9. Lee, Y. J.; Braun, P. V. Adv. Mater. 2003, 15, 563. https://doi.org/10.1002/adma.200304588
  10. Lin, S.-Y.; Chow, E.; Hietala, V.; Villeneuve, P. R.; Joannopoulos,J. D. Science 1998, 282, 274. https://doi.org/10.1126/science.282.5387.274
  11. Noda, S.; Tomoda, K.; Yamamoto, N.; Chutinan, A. Science 2000,289, 604. https://doi.org/10.1126/science.289.5479.604
  12. Campbell, M.; sharp, D. N.; Harrison, M. T.; Denning, R. G.; Turberfield,A. J. Nature 2000, 404, 53. https://doi.org/10.1038/35003523
  13. Jeon, S.; Park, J. U.; Cirelli, R.; Yang, S. M.; Heitzman, C. E.;Braun, P. V.; Kenis, P. J. A.; Rogers, J. A. Proc. Natl. Acad. Sci. USA 2004, 101, 12428. https://doi.org/10.1073/pnas.0403048101
  14. Griesebock, B.; Egen, M.; Zentel, R. Chem. Mater. 2002, 14, 4023. https://doi.org/10.1021/cm025613k
  15. Lee, W.; Chan, A.; Bevan, M. A.; Lewis, J. A.; Braun, P. V. Langmuir2004, 20, 5262. https://doi.org/10.1021/la035694e
  16. van Blaaderen, A.; Ruel, R.; Wiltzius, P. Nature 1997, 385, 321. https://doi.org/10.1038/385321a0
  17. Jiang, P.; Hwang, K. S.; Mittleman, D. M.; Bertone, J. F.; Colvin,V. L. J. Am. Chem. Soc. 1999, 121, 11630. https://doi.org/10.1021/ja9903476
  18. Jiang, P.; Ostojic, G. N.; Narat, R.; Mittleman, D. M.; Colvin, V. L.Adv. Mater. 2001, 13, 389. https://doi.org/10.1002/1521-4095(200103)13:6<389::AID-ADMA389>3.0.CO;2-L
  19. Velev, O. D.; Kaler, E. W. Adv. Mater. 2000, 12, 531. https://doi.org/10.1002/(SICI)1521-4095(200004)12:7<531::AID-ADMA531>3.0.CO;2-S
  20. Vlasov, Y. A.; Bo, X. Z.; Sturm, J. C.; Norris, D. J. Nature 2001,414, 289. https://doi.org/10.1038/35104529
  21. Xia, Y.; Gates, B.; Yin, Y.; Lu, Y. Adv. Mater. 2000, 12, 693. https://doi.org/10.1002/(SICI)1521-4095(200005)12:10<693::AID-ADMA693>3.0.CO;2-J
  22. Albota, M.; Beljonne, D.; Bredas, J.-L.; Ehrlich, J. E.; Fu, J.-Y.;Heikal, A. A.; Hess, S. E.; Kogej, T.; Levin, M. D.; Marder, S. R.;McCord-Maughon, D.; Perry, J. W.; Rockel, H.; Rumi, M.; Subramaniam,G.; Webb, W. W.; Wu, X.-L.; Xu, C. Science 1998, 281,1653. https://doi.org/10.1126/science.281.5383.1653
  23. Sun, H.-B.; Kawakami, T.; Xu, Y.; Ye, J.-Y.; Matuso, S.; Misawa,H.; Miwa, M.; Kaneko, R. Opt. Lett. 2000, 25, 1110. https://doi.org/10.1364/OL.25.001110
  24. Egen, M.; Zentel, R. Chem. Mater. 2002, 14, 2176. https://doi.org/10.1021/cm010375z
  25. Caruso, F. Colloids and Colloid Assemblies; Synthesis, Modification, Organization and Utilization of Colloid Particles; Wiley-VCH: Weinheim, 2003.
  26. Dong, H.; Lee, S. Y. Macromol. Res. 2009, 17, 397. https://doi.org/10.1007/BF03218880
  27. Goodwin, J. W.; Hearn, J.; Ottewill, R. H. Colloid Polym. Sci.1974, 252, 464. https://doi.org/10.1007/BF01554752
  28. Odian, G. Principles of Polymerization, 3rd ed.; John Wiley and Sons: New York, 1991.
  29. Checoury, X.; Enoch, S.; Lopez, C.; Blanco, A. Appl. Phys. Lett.2007, 90, 161131. https://doi.org/10.1063/1.2724916
  30. Lee, W.; Braun, P. V. Mater. Sci. Eng. C 2007, 27, 961. https://doi.org/10.1016/j.msec.2006.06.016
  31. Ma, X.; Lu, J. Q.; Brock, R. S.; Jacobs, K. M.; Yang, P.; Hu, X.Phys. Med. Biology 2003, 48, 4165. https://doi.org/10.1088/0031-9155/48/24/013

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