Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Structures and Photoluminescent Properties of Two Novel Zinc(II) Compounds Constructed from 5-Sulfoisophthalic Acid

  • Zhu, Yu-Lan (Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Normal University) ;
  • Tang, Xue-Ling (Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Normal University) ;
  • Ma, Kui-Rong (Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Normal University) ;
  • Chen, Hao (Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Normal University) ;
  • Ma, Feng (Department of Chemistry, College of Science, Yanbian University) ;
  • Zhao, Lian-Hua (Department of Chemistry, College of Science, Yanbian University)
  • Received : 2010.03.14
  • Accepted : 2010.04.17
  • Published : 2010.07.20
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Abstract

Hydrothermal reaction of zinc(II) salts with 5-sulfoisophthalic acid monosodium salt ($NaO_3SC_6H_3$-1,3-(COOH)$_2$, $NaH_2$-SIP) and 1,10-phenanthroline (phen) led to two new compounds, [Zn(phen)$_3$$\cdot2H_2SIP\cdot4H_2O$ (1) and [Zn(phen)$_2(H_2O)_2]\cdot2H_2SIP\cdot2H_2O$ (2). They were characterized by element analysis, IR spectroscopy, thermalgravimetric analysis (TGA), X-ray powder diffraction (XRD), and single-crystal X-ray diffraction. Both compounds 1-2 represent the first example of Zn/phen/SIP system. The Zn (II) ion in 1 is six-coordinated by six nitrogen atoms from three phen molecules, and the $H_2SIP^-$ ligands engage in the formation of hydrogen bond. The Zn(II) ion in 2 is coordinated by four nitrogen atoms from two phen molecules and two oxygen atoms from two water molecules. Moreover, both 1 and 2 are assembled into 3D supramolecular architectures by hydrogen bonds (O-H$\ldots$O) and $\pi-\pi$ interactions. Solvent water molecules occupying voids of the compounds serve as receptors or donors of the extensive O-H$\ldots$O hydrogen bonds.

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