통합자연과학논문집 (Journal of Integrative Natural Science)

조선대학교 기초과학연구원 (The Basic Science Institute Chosun University)
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Dehydrogenative Polymerization of Hydrosilanes to Silicon Polymers

  • Kim, Myoung-Hee (Nanotechnology Research Center and Department of Chemistry, Chonnam National University) ;
  • Lee, Jun (Nanotechnology Research Center and Department of Chemistry, Chonnam National University) ;
  • Mo, Soo-Yong (Nanotechnology Research Center and Department of Chemistry, Chonnam National University) ;
  • Kim, Jong-Hyun (Nanotechnology Research Center and Department of Chemistry, Chonnam National University) ;
  • Woo, Hee-Gweon (Nanotechnology Research Center and Department of Chemistry, Chonnam National University)
  • 투고 : 2010.06.08
  • 심사 : 2010.06.24
  • 발행 : 2010.06.30
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초록

Hydrosilanes possessing reactive Si-H bond are used in synthesizing various types of polysilanes by dehydrocoupling under the influence of various organometallic promoters. Catalytic Si-Si/Si-O coupling of hydrosilanes with hydrosilanes, alcohols, and lactones to silicon-based polymers are described in this article as selective examples of our recent research developments. These silicon-containing polymers can be used as a precursor to prepare useful functional materials for fabricating electronic devices.

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