Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Polymeric Membrane Silver-ion Selective Electrodes Based on Schiff Base N,N'-Bis(pyridin-2-ylmethylene)benzene-1,2-diamine

  • Received : 2010.02.10
  • Accepted : 2010.04.05
  • Published : 2010.06.20
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Abstract

The Schiff base N,N'-bis(pyridin-2-ylmethylene)benzene-1,2-diamine [BPBD] has been synthesized and explored as ionophore for preparing PVC-based membrane sensors selective to the silver ($Ag^+$) ion. Potentiometric investigations indicate high affinity of this receptor for silver ion. The best performance was shown by the membrane of composition (w/w) of ionophore: 1 mg, PVC: 33 mg, o-NPOE: 66 mg and additive were added 50 mol % relative to the ionophore in 1 mL THF. The sensor works well over a wide concentration range $1{\times}10^{-3}$ to $1.0{\times}10^{-7}$ M by pH 6 at room temperature (slope 58.6 mV/dec.) with a response time of 10 seconds and showed good selectivity to silver ion over a number of cations. It could be used successfully for the determination of silver ion content in environmental and waste water samples.

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