Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Kinetic Study of the Visible Light-Induced Sonophotocatalytic Degradation of MB Solution in the Presence of Fe/TiO2-MWCNT Catalyst

  • Zhang, Kan (Department of Advanced Materials & Science Engineering, Hanseo University) ;
  • Oh, Won-Chun (Department of Advanced Materials & Science Engineering, Hanseo University)
  • Received : 2010.02.14
  • Accepted : 2010.04.13
  • Published : 2010.06.20
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Abstract

In order to effective degradation of organic dye both under visible light or ultrasonic irradiation, the MWCNTs (multiwalled carbon nanotube) deposited with Fe and $TiO_2$ were prepared by a modified sol-gel method. The Fe/$TiO_2$-MWCNT catalyst was characterized by surface area of BET, scanning electron microscope (SEM), Transmission Electron Microscope (TEM), X-ray diffraction (XRD), and energy dispersive X-ray (EDX) and ultraviolet-visible (UV-vis) spectroscopy. The low intensity visible light and low power ultrasound was as an irradiation source and the methylene blue (MB) was choose as the model organic dye. Then degradation experiments were carried out in present of undoped $TiO_2$, Fe/$TiO_2$ and Fe/$TiO_2$-MWCNT catalysts. Through the degradation of MB solution, the results showed the feasible and potential use of Fe/$TiO_2$-MWCNT catalyst under visible light and ultrasonic irradiation due to the enhanced formation of reactive radicals as well as the possible visible light and the increase of ultrasound-induced active surface area of the catalyst. After addition of $H_2O_2$, the MB degradation rates have been accelerated, especially with Fe/$TiO_2$-MWCNT catalyst, in case of that the photo-Fenton reaction occurred. The sonophotocatalysis was always faster than the respective individual processes due to the more formation of reactive radicals as well as the increase of the active surface area of Fe/$TiO_2$-MWCNT catalyst.

Keywords

References

  1. Berlan, J.; Trabelsi, F.; Delmas, H.; Wilhelm, A. M.; Petrignani,J. F. Ultrason. Sonochem. 1994, 1, 97. https://doi.org/10.1016/1350-4177(94)90005-1
  2. Gogate, P. R. Adv. Environ. Res. 2002, 6, 335. https://doi.org/10.1016/S1093-0191(01)00067-3
  3. Suslick, K. S. Scientific American 1989, 260, 80.
  4. Makino, K.; Mossoba, M. M.; Riesz, P. J. Phys. Chem. 1983, 87,1369. https://doi.org/10.1021/j100231a020
  5. Serpone, N.; Colarusso, P. Res. Chem. Intermed. 1994, 20, 635. https://doi.org/10.1163/156856794X00261
  6. Riesz, P.; Berdahl, D.; Christman, C. L. Environ. Health Perspect.1985, 64, 233. https://doi.org/10.2307/3430013
  7. Silva, C. G.; Faria, J. L. J. Photochem. Photobiol. A 2003, 155,133. https://doi.org/10.1016/S1010-6030(02)00374-X
  8. Han, W.; Zhu, W.; Zhang, P.; Zhang, Y.; Li, L. Catal. Today 2004,90, 319. https://doi.org/10.1016/j.cattod.2004.04.041
  9. Han, W.; Zhang, P.; Zhu, W.; Yin, J.; Li, L. Water. Res. 2004, 38,4197. https://doi.org/10.1016/j.watres.2004.07.019
  10. He, D. M.; Yang, L. X.; Kuang, S. Y.; Cai, Q. Y. Electrochem. Communications2007, 9, 2467. https://doi.org/10.1016/j.elecom.2007.07.025
  11. Zhang, X. W.; Zhou, M. H.; Lei, L. C. Mater. Chem. Phys. 2005,91, 73. https://doi.org/10.1016/j.matchemphys.2004.10.058
  12. Feng, J.; Wong, R. S. K.; Hu, X.; Yue, P. L. Catal. Today 2004, 98,441. https://doi.org/10.1016/j.cattod.2004.08.007
  13. Wang, W. D.; Serp, P.; Kalck, P.; Faria, J. L. Appl. Catal. B: Environ.2005, 56, 305. https://doi.org/10.1016/j.apcatb.2004.09.018
  14. Ohno, T.; Akiyoshi, M.; Umebayashi, T.; Asai, K.; Mitsui, T.; Matsumura,M. Appl. Catal. A: General 2004, 265, 115. https://doi.org/10.1016/j.apcata.2004.01.007
  15. Tryba, B. J. Hazard. Mater. 2008, 151, 623. https://doi.org/10.1016/j.jhazmat.2007.06.034
  16. Yang, X.; Cao, C.; Hohn, K.; Erickson, L.; Maghirang, R.; Klabunde,K. J. Catal. 2007, 252, 296. https://doi.org/10.1016/j.jcat.2007.09.014
  17. Teoh, W. Y.; Amal, R.; Mädler, L.; Pratsinis, S. E. Catal. Today2007, 120, 203. https://doi.org/10.1016/j.cattod.2006.07.049
  18. Wang, W. D.; Serp, P.; Kalck, P.; Faria, J. L. J. Mole. Catal. A: Chem. 2005, 235, 194. https://doi.org/10.1016/j.molcata.2005.02.027
  19. Tuziuti, T.; Yasui, K.; Iida, Y.; Taoda, H.; Koda, S. Ultrason. 2004,42, 597. https://doi.org/10.1016/j.ultras.2004.01.082
  20. Wang, J.; Lv, Y. H.; Zhang, Z. H.; Deng, Y. Q.; Zhang, L. Q.; Liu,B.; Xu, R.; Zhang, X. D. J. Haz. Mater. 2009, 170, b398. https://doi.org/10.1016/j.jhazmat.2009.04.083
  21. Wang, J.; Sun, W.; Zhang, Z. H.; Jiang, Z.; Wang, X. F.; Xu, R.; Li,R. H.; Zhang, X. D. J. Col. Inter. Sci. 2008, 320, 202. https://doi.org/10.1016/j.jcis.2007.12.013
  22. Berberidou, C.; Poulios, I.; Xekoukoulotakis, N. P.; Mantzavinos,D. Appl. Catal. B: Environ. 2007, 74, 63. https://doi.org/10.1016/j.apcatb.2007.01.013
  23. Yano, J.; Matsuura, J.; Ohura, H.; Yamasaki, S. Ultrason. Sonochem.2005, 12, 197. https://doi.org/10.1016/j.ultsonch.2003.12.001
  24. Oh, W. C.; Zhang, F. J.; Chen, M. L.; Lee, Y. M.; Ko, W. B. J. Ind. Eng. Chem. 2009, 15, 190. https://doi.org/10.1021/ie50158a034
  25. Zhang, K.; Oh, W. C. J. Kor. Cer. Soc. 2009, 46, 561. https://doi.org/10.4191/KCERS.2009.46.6.561
  26. Oh, W. C.; Chen, M. L. Bull. Kor. Chem. Soc. 2008, 29, 159. https://doi.org/10.5012/bkcs.2008.29.1.159
  27. Wang, J.; Ma, T.; Zhang, Z. H.; Zhang, X. D.; Jiang, Y. F.; Pan, Z.J.; Wen, F. Y.; Kang, P. L.; Zhang, P. Desalination 2006, 195, 294. https://doi.org/10.1016/j.desal.2005.12.007
  28. Hung, W. C.; Chen, Y. C.; Chu, H.; Tseng, T. K. Appl. Sur. Sci.2008, 255, 2205. https://doi.org/10.1016/j.apsusc.2008.07.079
  29. Chen, L. C.; Ho, Y. C.; Guo, W. S.; Huang, C. M.; Pan, T. C.; Electrochimica. Acta 2009, 54, 3884. https://doi.org/10.1016/j.electacta.2009.02.001
  30. Zhang, K.; Meng, Z. D.; Ko, W. B.; Oh, W. C. Anal. Sci. Technol.2009, 22, 254.
  31. Wu, K. Q.; Xie, Y. D.; Zhao, J. C.; Hidaka, H. S. J. Mol. Catal. A1999, 144, 77. https://doi.org/10.1016/S1381-1169(98)00354-9
  32. Rincon, A. G.; Pulgarin, C. Appl. Catal. B 2006, 63, 222. https://doi.org/10.1016/j.apcatb.2005.10.009
  33. Zhang, K.; Oh, W. C. Kor. J. Mater. Res. 2009, 19, 481. https://doi.org/10.3740/MRSK.2009.19.9.481
  34. Tryba, B.; Morawski, A. W.; Inagaki, M.; Toyoda, M. Chemosphere2006, 64, 1225. https://doi.org/10.1016/j.chemosphere.2005.11.035
  35. Mrowetz, M.; Pirola, C.; Selli, E. Ultrason. Sonochem. 2003, 10,247. https://doi.org/10.1016/S1350-4177(03)00090-7
  36. Shimizu, N.; Ogino, C.; Dadjour, M. F.; Murata, T. Ultrason. Sonochem.2007, 14, 184. https://doi.org/10.1016/j.ultsonch.2006.04.002
  37. Tu, Y. F.; Huang, S. Y.; Sang, J. P.; Zou, X. W. Mater. Res. Bull.2010, 45, 224. https://doi.org/10.1016/j.materresbull.2009.08.020

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