한국수소및신에너지학회논문집 (Journal of Hydrogen and New Energy)

  • 제21권1호
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  • Pages.58-63
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  • 2010
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  • 1738-7264(pISSN)
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  • 2288-7407(eISSN)
한국수소및신에너지학회 (The Korean Hydrogen and New Energy Society)
권호 표지

수소 가압형 기계적 합금화법에 의한 $MgH_x-V_2O_5$ 복합재료의 수소와 특성

Hydrogenation Properties of $MgH_x-V_2O_5$ Composites by Hydrogen Induced Mechanical Alloying

  • 정미원 (성신여자대학교 생명과학.화학부) ;
  • 박지희 (성신여자대학교 생명과학.화학부) ;
  • 조경원 (충북대학교 신소재공학과) ;
  • 김경일 (충주대학교 신소재공학과/친환경에너지 부품 연구센터) ;
  • 최재하 (충북대학교 신소재공학과) ;
  • 김상헌 (한밭대학교 응용화학생명공학부) ;
  • 홍태환 (충주대학교 신소재공학과 / 친환경에너지 부품 연구센터)
  • Jung, Mie-Won (School of Biological Sciences and Chemistry, Sungshin Women's Univ.) ;
  • Park, Ji-Hee (School of Biological Sciences and Chemistry, Sungshin Women's Univ.) ;
  • Cho, Kyoung-Won (Dept. of Advanced Materials Engineering, Chungbuk National Univ.) ;
  • Kim, Kyeong-Il (Dept. of Materials Science and Engineering/Research Center for Sustainable Eco-Devices and Materials(ReSEM), Chungju National Univ.) ;
  • Choi, Jae-Ha (Dept. of Advanced Materials Engineering, Chungbuk National Univ.) ;
  • Kim, Sang-Hern (Division of Applied Chemistry & Biotechnology, Hanbat National Univ.) ;
  • Hong, Tae-Whan (Dept. of Materials Science and Engineering/Research Center for Sustainable Eco-Devices and Materials(ReSEM), Chungju National Univ.)
  • 발행 : 2010.02.28
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초록

Mg and Ma-based alloys are promising hydrogen storage materials for renewable clean energy applications. It has high hydrogen storage capacity (7.6wt.%), lightweight and low economical materials. However, commercial applications of the Mg hydride are currently hindered by its high operating temperature, and very slow reaction kinetics. In this work, we are aimed at studying the hydrogenation properties of the $MgH_x-V_2O_5$ composite prepared by hydrogen induced mechanical alloying. The absorption capacity of the sample is found to be about 4.7wt.% at 623K under 3 MPa $H_2$ pressure. The absorption characteristics observed have been compared with prepared $MgH_x$.

키워드

참고문헌

  1. G. Barkhordarian, T. Klassen, R. Bormann, "Fast hydrogen sorption kinetics of nanocrystalline Mg using $Nb_{2}O_{5}$ as catalyst", Scripta Mater., Vol. 49, No. 1, 2003, pp. 213-217. https://doi.org/10.1016/S1359-6462(03)00259-8
  2. A.R. Yavari, A. LeMoulec, F.R. de Castro, S. Deledda, O. Friedrichs, W.J. Botta, G. Vaughan, T. Klassen, A. Fernandez, A. Kvick, "Improvement in H-sorption kinetics of $MgH_{2}$ powders by using Fe nanoparticles generated by reactive $FeF_{3}$addition", Scripta Mater., Vol. 52, No.8, 2005, pp. 719-724. https://doi.org/10.1016/j.scriptamat.2004.12.020
  3. J.-L. Bobet, F.J. Castro, B. Chevalier, "Effects of RMG conditions on the hydrogen sorption properties of $Mg+Cr_{2}O_{3}$mixtures", Scripta Mater., Vol. 52, No.1, 2005, pp. 33-37. https://doi.org/10.1016/j.scriptamat.2004.09.001
  4. J.-L. Bobet, B. Chevalier, M.Y. Song, B. Darriet, "Improvements of hydrogen storage properties of Mg-based mixtures elaborated by reactive mechanical milling", J. Alloys Compd., Vol. 356-357, 2003, pp. 570-574. https://doi.org/10.1016/S0925-8388(02)01279-3
  5. M.Y. Song, I.H. Kwon, J.-S. Bae, "Development of hydrogen-storage alloys of Mg - $Fe_{2}O_{3}$ system by reactive mechanical grinding", Int. J Hydrogen Energy, Vol. 30, No. 10, 2005, pp. 1107-1111. https://doi.org/10.1016/j.ijhydene.2004.10.019
  6. J.F. Pelletier, J. Huot, M Sutton, R. Schulz, A.R. Sandy, L.B. Lurio, S.G.J. Mochrie, "Investigation of dehydrogenation mechanism of $MgH_{2}$ - Nb nanocomposites", J Alloys Compd., Vol. 348, No. 1-2, 2003, pp. 319-324. https://doi.org/10.1016/S0925-8388(02)00839-3
  7. C.X. Shang, M. Bououdina, Y. Song, Z.X. Guo, "Mechanical alloying and electronic simulations of ($MgH_{2}$+M) systems (M=Al, Ti, Fe, Ni, Cu and Nb) for hydrogen storage", Int. J. Hydrogen Energy, Vol. 29, No.1, 2004, pp. 73-80. https://doi.org/10.1016/S0360-3199(03)00045-4
  8. W. Oelerich, T. Klassen, R. Bormann, "Metal oxides as catalysts for improved hydrogen sorption in nanocrystalline Mg-based materials", J. Alloys Compd., Vol. 315, No. 1-2, 2001, pp. 237-242. https://doi.org/10.1016/S0925-8388(00)01284-6
  9. G. Laing, J. Huot, S. Boily, A Van Neste, R. Schulz, "Hydrogen storage properties of the mechanically milled $MgH_{2}$ - V nanocomposite", J. Alloys Compd., Vol. 291, No. 1-2, 1999, pp. 295-299. https://doi.org/10.1016/S0925-8388(99)00268-6
  10. G. Laing, J. Huot, S. Boily, A. Van Neste, R. Schulz, "Catalytic effect of transition metals on hydrogen sorption in nanocrystalline ball milled $MgH_{2}$-Tm (Tm=Ti, V, Mn, Fe and Ni) systems", J. Alloys Compd., Vol. 292, No. 1-2, 1999, pp. 247-252. https://doi.org/10.1016/S0925-8388(99)00442-9
  11. V. V. Bhat, A. Rougier, L. Aymard, G. A. Nari, J.-M Tarascon, "High surface area niobium oxides as catalysts for improved hydrogen sorption properties of ball milled $MgH_{2}$,", J. Alloys Compd., Vol. 460, No. 1-2, 2008, pp. 507-512. https://doi.org/10.1016/j.jallcom.2007.05.084
  12. Kyeong-II Kim, Tae-Whan Hong, "Evaluations of Hydrogen Properties on $MgH_{x}Nb_{2}$O_{5}$, Composite by Mechanical Alloying", Materials Science Forum, Vol. 620-622, 2009, pp.9-12. https://doi.org/10.4028/www.scientific.net/MSF.620-622.9