DOI QR코드

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탄화규소 나노섬유의 고온 대기 및 SO2 가스분위기에서의 부식물성

Characterization of Air and SO2 Gas Corrosion of Silicon Carbide Nanofibers

  • 김민정 (성균관대학교 신소재공학과) ;
  • 이동복 (성균관대학교 신소재공학과)
  • Kim, Min-Jung (School of Advanced Materials Science & Engineering, Sungkyunkwan University) ;
  • Lee, Dong-Bok (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
  • 발행 : 2010.02.28

초록

The SiO vapor that was generated from a mixture of Si and $SiO_2$ was reacted at $1350^{\circ}C$ for 2 h under vacuum with carbon nanofibers to produce SiC nanofibers having an average diameter of 100~200 nm. In order to understand the gas corrosion behavior, SiC nanofibers were exposed to air up to $1000^{\circ}C$. SiC oxidized to amorphous $SiO_2$, but its oxidation resistance was inferior unlike bulk SiC, because of high surface area of nanofibers. When SiC nanofibers were exposed to Ar-1% $SO_2$ atmosphere, SiC oxidized to amorphous $SiO_2$, without forming $SiS_2$, owing to the thermodynamic stability of $SiO_2$.

키워드

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