Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Studies of Inter/intramolecular Weak Interactions with CH… S; and S…arene Interaction in Symmetrical and Dissymmetrical Models

  • Dubey, Rashmi (Department of Chemistry, Faculty of Science, Banaras Hindu University) ;
  • Tewari, Ashish K. (Department of Chemistry, Faculty of Science, Banaras Hindu University) ;
  • Ravikumar, K. (Laboratory of X-ray Crystallography, Indian Institute of Chemical Technology) ;
  • Sridhar, B. (Laboratory of X-ray Crystallography, Indian Institute of Chemical Technology)
  • Received : 2009.10.14
  • Accepted : 2010.03.18
  • Published : 2010.05.20
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Abstract

Evidences have proved the versatile role of sulfur atom in supramolecular chemistry. $^1$Presence of S atom in the molecule usually results in the specific structural properties of molecules. In the present study, $S{\cdots}arene$, $N{\cdots}arene$, $CH{\cdots}{\pi}$, $CH{\cdots}S$ and $CH{\cdots}N$ type of weak interactions stabilize the conformation and self assembly of symmetrical as well as dissymmetrical molecules.

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References

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