Bulletin of the Korean Chemical Society

  • 제31권5호
  • /
  • Pages.1280-1282
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  • 2010
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Asymmetric Michael Addition of Ketones to Nitroolefins Catalyzed by a New Chiral Catalyst

  • Wang, Lian-Jun (College of Chemistry and Chemical Engineering, Hunan Institute of Engineering) ;
  • Hu, Feng-Feng (College of Chemistry and Chemical Engineering, Hunan Institute of Engineering)
  • 투고 : 2010.02.11
  • 심사 : 2010.03.13
  • 발행 : 2010.05.20
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초록

A new chiral catalyst was synthesized and found that it could catalyzed the asymmetric Michael reaction of ketones with nitroolefins smoothly at room temperature, giving the desired adducts in 71 - 92% yields with excellent diastereoselectivities and high enantioselectivities (up to 95% ee).

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참고문헌

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  2. A Novel Proline-based Acridone Bifunctional Organocatalyst for the Asymmetric Michael Addition of Cyclohexanone vol.47, pp.4, 2018, https://doi.org/10.1246/cl.171220
  3. ChemInform Abstract: Asymmetric Michael Addition of Ketones to Nitroolefins Catalyzed by a New Chiral Catalyst. vol.41, pp.40, 2010, https://doi.org/10.1002/chin.201040027
  4. Hydrogen‐Bonding in Aminocatalysis: From Proline and Beyond vol.20, pp.2, 2010, https://doi.org/10.1002/chem.201303982
  5. Proline‐derived Long‐aliphatic‐chain Amphiphilic Organocatalysts (PDLACAOs) for Asymmetric Reactions in Aqueous Media vol.9, pp.11, 2010, https://doi.org/10.1002/ajoc.202000419