DOI QR코드

DOI QR Code

Synthesis of Li2Mn3O7 and Application to Hybrid Capacitor

  • Received : 2010.12.13
  • Accepted : 2010.12.28
  • Published : 2010.12.30

Abstract

In order to apply hybrid capacitor, $Li_2Mn_3O_7$ was synthesized by combustion method using $LiNO_3$, $Li(CH_3COO){\cdot}2H_2O$ and $Mn(CH_3COO){\cdot}4H_2O$. Spinel pattern was identified the samples calcined over $400^{\circ}C$ in XRD. Intensity of $Mn_2O_3$ peak increased as the calcination temperature increased. To decide n/p ratio and to investigate electrochemical properties, charge-discharge tests of Li/$Li_2Mn_3O_7$ and Li/AC half-cell were carried out. Applying to AC/$Li_2Mn_3O_7$ hybrid capacitor, it had high discharge capacitance of 32.8 F/cc at 100 mA/g.

Keywords

References

  1. Y.J. Hao, Y.Y. Wang, Q.Y. Lai, Y. Zhao, L.M. Chen and X.Y. Ji, J. Solid State Electrochem., 13, 905 (2009). https://doi.org/10.1007/s10008-008-0627-y
  2. H.Y. Chu, Q.Y. Lai, Y.J. Hao, Y. Zhao and X.Y. Xu, J. Appl. Electrochem., 39, 2207 (2009).
  3. Y. Zhao, X.Y. Xu, Q.Y. Lai, Y.J. Hao, L. Wang and Z. Lin, J. Solid State Electrochem., 14, 1509 (2010). https://doi.org/10.1007/s10008-009-0970-7
  4. H.U. Kim, Y.-K. Sun, K.H. Shin and C.S. Jin, Phys. Scr., T139, 014053 (2010). https://doi.org/10.1088/0031-8949/2010/T139/014053
  5. H.U. Kim, Y.-K. Sun, B.-S. Lee, C.S. Jin and K.Y. Shin, J. Kor. Electrochem. Soc., 13, 103 (2010). https://doi.org/10.5229/JKES.2010.13.2.103
  6. M.M. Thackeray, Prog. Solid St. Chem., 25, 1 (1997). https://doi.org/10.1016/S0079-6786(97)81003-5
  7. Y.J. Shin and A. Manthiram, Electrochim. Acta, 48, 3583 (2003). https://doi.org/10.1016/S0013-4686(03)00478-X
  8. T. Takada, H. Hayakawa, E. Akiba, F. Izumi and B.C. Chakoumakos, J. Power Sources, 68, 613 (1997). https://doi.org/10.1016/S0378-7753(96)02570-0
  9. J.P. Zheng, J. Electrochemical Soc., 150, A48 (2003).
  10. T. Takada, H. Hayakawa and E. Akiba, J. Solid State Chem., 115, 420 (1995). https://doi.org/10.1006/jssc.1995.1154
  11. T. Takada, H. Hayakawa, T. Kumagai and E. Akiba, J. Solid State Chem., 121, 79 (1996). https://doi.org/10.1006/jssc.1996.0012
  12. M.M. Thackeray, M.F. Mansuetto and C.S. Johnson, J. Solid State Chem., 125, 274 (1996). https://doi.org/10.1006/jssc.1996.0297
  13. M.M. Thackeray, A de Kock and W.I.F. David, Mater. Res, Bull., 28, 1041 (1993). https://doi.org/10.1016/0025-5408(93)90142-Z

Cited by

  1. Synthesis and Electrochemical Characteristics of Spherical Li4Ti5O12/CNT Composite Materials for Hybrid Capacitors vol.6, pp.2, 2015, https://doi.org/10.5229/JECST.2015.6.2.59
  2. Phase equilibria involving solid solutions in the Li–Mn–O system vol.62, pp.5, 2017, https://doi.org/10.1134/S0036023617050059