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스핀코팅으로 제작된 Cu2O 필름의 광전기적 특성

Optoelectronic Characteristics of Transparent Cu2O Films Spin-coated on Glass Substrates

  • 곽기열 (고려대학교 미세소자공학협동) ;
  • 조경아 (고려대학교 전기전자전파공학부) ;
  • 김상식 (고려대학교 전기전자전파공학부)
  • 발행 : 2010.01.01

초록

$Cu_2O$ nanoparticles-based films are fabricated by spin-coating on glass substrates and their optoelectronic characteristics are investigated in this study. The $Cu_2O$ films are nearly all-transparent as high as 98% in a wavelength range from 400 nm to 900 nm and three exciton peaks associated with the sublevels in the conduction band are observed at the wavelengths shorter than 400 nm in the absorption spectrum. Under the illumination of the 325 nm wavelength light, the photocurrent efficiency of the $Cu_2O$ film is $1.8\times10^5 {\mu}A/W$ at a voltage of 2.5 V in air.

키워드

참고문헌

  1. K. Borgohin, N. Murase, S. J. Mahamunia, "Synthesis and properties of $Cu_2O$ quantum particles", J. Appl. Phys., vol.92, no.3, pp.1292-1297, Aug. 2002. https://doi.org/10.1063/1.1491020
  2. Mangamma G, Hayaraman V, Gnanaseharan T, Peryasamy G, "Effects of silica additions on $H_2S$ sensing properties of CuO-$SnO_2$ sensors", Sens. Actuator B-Chem., vol.35, no.3, pp.133-139, Dec. 1998.
  3. Kosuke Matsuzaki, Kenji Nomura, Hiroshi Yanagi, Toshio Kamiya, Masahiro Hirano, Hideo Hosono, "Epitaxial growth of high mobility $Cu_2O$ thin films and application to p-channel thin film transistor", Appl. Phys, Lett., vol.93, p.202107, Nov. 2008. https://doi.org/10.1063/1.3026539
  4. Y. Dong, Y. Li, C. Wang, A. Cui, Z. Deng, K. Borgohin, N. Murase, S. J. Mahamunia, "Preparation of Cuprous Oxide Particles of Different Crystallinity", J. Colloid Interface Sci., vol.243, pp.85-89, Sep. 2001. https://doi.org/10.1006/jcis.2001.7857
  5. S. Ram, C. Mitra, "Formation of stable $Cu_2O$ nanocrystals in a new orthorhombic crystal structure", Mater. Sci. Eng. A-Struct. Mater. Prop. Microstruct. Process., vol.A 304, pp.805-809, 2001.
  6. E. W. Bohannan, M. G. Shumsky, J. A. Switzer, "Epitaxial Electrodeposition of Copper(I) Oxide on Single-Crystal Gold(100)", Chem. Mat., vol.11, pp.2289-2291, Jan. 2001.
  7. Ming Yin, Chun-Kwei Wu, Yongbing Lou, Clemens Burda, Jeffrey T. Koberstein, Yimei Zhu, Stephen O'Brien, "Copper Oxide Nanocrystals", J. Am. Chem. Soc., vol.207, pp.9506, Oct. 2005.
  8. I. Grozdanov, "Electroless chemical deposition technique for $Cu_2O$ thin films", Mater. Lett., vol.19, no.5-6, pp.284-285, May. 1994.
  9. T. Mahalingam, J. S. P. Chitra, J. P. Chu, and P. J. Sebastian, "Preparation and microstructural studies of electrodeposited $Cu_2O$ thin films", Mater. Lett., vol.58, no.11, pp.1802-1807, Apr. 2004. https://doi.org/10.1016/j.matlet.2003.10.055
  10. A. Richthofen, R. Domnick, R. Cremer, "Preparation of cuprite ($Cu_2O$), paramelaconite (${CU_3}^{2+}{CU_2}^{1+}O_4$) and tenorite (CuO) with magnetron sputtering ion plating: characterization by EPMA, XRD, HEED and SEM", Fresenius' Journal of Analytical Chemistry, vol.358, no.1-2, pp.312-315, May. 1997. https://doi.org/10.1007/s002160050415
  11. Xuan Wang, Linjie Zhi, and Klaus Mullen, "Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells", Nano Lett., vol.8, no.1, pp.323-327, Dec. 2007.
  12. Susmita Kundu, Sunirmal Jana, Prasanta Kumar Biswas, "Quantum confinement effect of in-situ generated $CU_2O$ in a nanostructured zirconia matrix", Mater. Sci., vol.23, no.1, pp.7-14, Sep. 2005.
  13. Y L Liu, Y C Liu, R Mu, H Yang, C L Shao, J Y Zhang, Y M Lu, D Z Shen, X W Fan, "The structural and optical properties of $CU_2O$ films electrodeposited on different substrates", Semicond. Sci. Technol., vol.20, pp.44-49, Dec. 2004.