Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Terphenyls and Quaterphenyls via the Nickel N-Heterocyclic Carbene-Catalyzed Cross-Coupling of Neopentyl Arenesulfonates with Aryl Grignard Reagents

  • Jo, Hyun-Jong (School of Chemical Engineering and Materials Science, Chung-Ang University) ;
  • Kim, Chul-Bae (School of Chemical Engineering and Materials Science, Chung-Ang University) ;
  • Ryoo, Tae-Yong (School of Chemical Engineering and Materials Science, Chung-Ang University) ;
  • Ahn, Bo-Kyoung (School of Chemical Engineering and Materials Science, Chung-Ang University) ;
  • Park, Kwang-Yong (School of Chemical Engineering and Materials Science, Chung-Ang University)
  • Received : 2010.09.10
  • Accepted : 2010.10.21
  • Published : 2010.12.20
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Abstract

Various terphenyl and quaterphenyl derivatives were prepared by the Ni-NHC catalyzed cross coupling of the corresponding biphenyl- and terphenyl-sulfonates with arylmagnesium bromides. The reactions proceeded rapidly via a nucleophilic aromatic substitution of the alkoxysulfonyl moieties by the aryl nucleophiles to afford high yields within just 1.5 h at room temperature in spite of the low reactivity of the sulfur electrophiles.

Keywords

References

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