Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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New 7-Hydroxycoumarin-Based Fluorescent Chemosensors for Zn(II) and Cd(II)

  • Swamy, K.M.K. (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University) ;
  • Kim, Min-Jung (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University) ;
  • Jeon, Hye-Ryeong (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University) ;
  • Jung, Ji-Young (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University) ;
  • Yoon, Ju-Young (Department of Chemistry and Nano Science (BK21) and Department of Bioinspired Science (WCU), Ewha Womans University)
  • Received : 2010.09.03
  • Accepted : 2010.10.04
  • Published : 2010.12.20
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Abstract

Five new 4- or 8-substituted-7-hydroxycoumarin derivatives (1-5) were synthesized as fluorescent sensors for metal ions. Fluorescent changes and selectivity for metal ions were compared based on the introduction of different ligands and/or testing with different substitution positions of 7-hydroxycoumarin in aqueous solution. Especially, probes 2, 3 and 5 displayed large fluorescence enhancements with $Zn^{2+}$ and $Cd^{2+}$. Probes 2 and 3 showed moderate selectivity for $Zn^{2+}$ over $Cd^{2+}$. On the other hand, probe 4 showed large fluorescence quenching effects upon the addition of $Ag^+$ and $Hg^{2+}$.

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References

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