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The Influence of Firing Conditions on the Color Properties of Pr-ZrSiO4 Pigments Synthesized Using Rice Husk Ash

  • Pyon, Kyu-Ri (Department of Material Science & Engineering, Myongji University) ;
  • Lee, Byung-Ha (Department of Material Science & Engineering, Myongji University)
  • 발행 : 2009.07.31

초록

Using rice husk ash as silica, the influence of the firing temperature and holding time on the color intensity of Pr-$ZrSiO_4$ pigments were investigated. The Pr-yellow pigments were calcined at 500, 700, 800, 900, 950, 1000, $1100^{\circ}C$ in a ceramic method. The synthesized pigments were characterized by DT-TG thermal analysis, X-ray diffraction, UV-Vis spectroscopy, and SEMEDAX analysis. The relationship between the zircon phase-formation growth and Pr-yellow color development was evaluated and the optimum firing conditions were determined. The color of the pigment samples was characterized on the grounds of the Commission Internationale de l'Eclairage (CIE) standard procedure (CIE $L^*a^*b^*$ measurement) after an application on the bisque ceramic tile.

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참고문헌

  1. G. D. Nero, G. Cappelletti, S. Ardizzone, P. Fermo, and S. Gilardoni, 'Yellow Pr-Zircon Pigments The Role of Praseodymium and of the Mineralizer,' J. Euro. Ceram. Soc., 24 [14] 3603-11 (2004) https://doi.org/10.1016/j.jeurceramsoc.2004.01.003
  2. K. R. Pyon and B. H. Lee, 'Effect of Iron Content and Annealing Temperature on the Color Characteristics of Fe-$ZrSiO_4$ Coral Pink Pigments Synthesized by Sol-gel Method,' J. Ceram. Soc. Jpn., 117 [3] 258-63 (2009) https://doi.org/10.2109/jcersj2.117.258
  3. K. Hill and R. Lehman, 'Effects of Selected Processing Variables on Color Formation in Praseodymium-Doped Zircon Pigments,' J. Am. Ceram. Soc., 83 [9] 2177-82 (2000) https://doi.org/10.1111/j.1151-2916.2000.tb01532.x
  4. M. Llusar, J. B. Vicent, J. Badenes, M. A. Tena, and G. Monros, 'Environmental Optimisation of Blue Vanadium Zircon Ceramic Pigment,' J. Euro. Ceram. Soc., 19 [15] 2647-57 (1999) https://doi.org/10.1016/S0955-2219(99)00041-2
  5. M. Shoyama, H. Nasu, and K. Kamiya, 'Preparation of Rare Earth-Zircon Pigments by the Sol-Gel Method,' J. Ceram. Soc. Jpn., 106 [3] 279-84 (1998) https://doi.org/10.2109/jcersj.106.279
  6. M. Shoyama, K. Hashimoto, T. Hashimoto, H. Nasu, and K. Kamiya, 'Iron-Zircon Pigments Prepared by the Sol-Gel Method,' J. Ceram. Soc. Jpn., 107 [6] 534-40 (1999) https://doi.org/10.2109/jcersj.107.534
  7. E. Kato and H. Takashima, 'Study of Zircon Pigments-Vanadium Blue,' Rep. Gov. Ind. Res. Inst, Nagoya, 4 [2] 147-50 (1956)
  8. C. A. Seabright, Yellow Pigments for Ceramic Ware, US Patent 2,992,123 (1961)
  9. R. A. Eppler, 'Mechanism of Formation of Zircon Stains,' J. Am. Ceram. Soc., 53 [8] 457-62 (1970) https://doi.org/10.1111/j.1151-2916.1970.tb12677.x
  10. M. Trojan, Synthesis of Yellow Pigments, Dyes and Pigments, 9 [4] 261-73 (1988) https://doi.org/10.1016/0143-7208(88)85015-0
  11. M. Ocana, A. Caballero, A. R. Gonzalez-Elipe, and P. Tartaj, C. J. Serna, 'Valence and Localization in Pr-doped zircon,' J. Solid State Chem., 139 [2] 412-15 (1998) https://doi.org/10.1006/jssc.1998.7875
  12. M. Ocana, A. Caballero, A. R. Gonzalez-Elipe, P. Tartaj, C. J. Serna, and R. I. Merino, 'The Effects of the NaF Flux on the Oxidation State and Localisation of Praseodymium in Pr-doped Zircon Pigments,' J. Euro. Ceram. Soc., 19 [5] 641-48 (1999) https://doi.org/10.1016/S0955-2219(98)00233-7
  13. J. A. Badenes, J. B. Vicent, M. Llusar, M. A. Tena, and G. Monros, 'The Nature of Pr-$ZrSiO_4$ Yellow Ceramic Pigment,' J. Mater. Sci., 37 [7] 1413-20 (2002) https://doi.org/10.1023/A:1014537000690
  14. S. J. Park, M. H. Kim, and Y. K. Choi, 'Wet Fine Grinding of Rice Husk Ash using a Stirred Ball Mill,' J. Biosystem Eng., 31 [1] 33-38 (2006) https://doi.org/10.5307/JBE.2006.31.1.033
  15. V. P. Della, I. Kuhn, and D. Hotza, 'Rice Husk Ash as an Alternate Source for Active Silica Production,' Mater. Lett., 57 [4] 818-21 (2002) https://doi.org/10.1016/S0167-577X(02)00879-0
  16. Y. Q. Zhao and S. F. Qingge, 'The Effect of Highly Reactive Rice Husk Ash on the Strength and Durability of Concrete,' J. Wuhan. Univ. Tech., 25 [2] 15-19 (2003)
  17. K. Ganesan, K. Rajagopal, and K. Thangavel, 'Rice Husk Ash Blended Cement: Assessment of Optimal Level of Replacement for Strength and Permeability Properties of Concrete,' Construction and Building Materials, 22 [8] 1675-83 (2008) https://doi.org/10.1016/j.conbuildmat.2007.06.011
  18. E. A. Basha, R. Hashim, and H. B. Mahmud, 'Stabilization of Residual Soil with Rice Husk Ash and Cement,' Construction & Building Materials, 19 [6] 448-53 (2005) https://doi.org/10.1016/j.conbuildmat.2004.08.001
  19. R. F. Abreu and J. Schneider, 'Structure and Hydration Kinetics of Silica Particles in Rice Husk Ash Studied by $^{29}Si$ High-Resolution Nuclear Magnetic Resonance,' J. Am. Ceram. Soc., 88 [6] 1514-20 (2005) https://doi.org/10.1111/j.1551-2916.2005.00302.x
  20. C. S. Prasad, K. N. Maiti, and R. Venugopal, 'Effect of Rice Husk Ash in Whiteware Compositions,' Ceram. Inter., 27 [6] 629-35 (2001) https://doi.org/10.1016/S0272-8842(01)00010-4
  21. F. Bondioli, F. Andreola, L. Barbieri, T. Manfredini, and A. M. Ferrari, 'Effect of Rice Husk Ash (RHA) in the Synthesis of (Pr,Zr)$SiO_4$ Ceramic Pigment,' J. Euro. Ceram. Soc., 27 [12] 3483-88 (2007) https://doi.org/10.1016/j.jeurceramsoc.2007.01.019
  22. Y. Kanno, 'Thermodynamic and Crystallographic Discussion of the Formation and Dissociation of Zircon,' J. Mater. Sci., 24 [7] 2415-20 (1989) https://doi.org/10.1007/BF01174504
  23. Y. C. Shin, D. Y. Shin, S. M. Han, and I. T. Nam, 'Synthesis of $ZrSiO_4$ Powders by the Sol-Gel Process,' J. Kor. Ceram. Soc., 32 [7] 853-57 (1995)
  24. T. Mori, H. Hoshino, Y. Ishikawa, H. Yamamura, H. Kobayashi, and T. Mitamura, 'Preparation of $ZrSiO_4$ Powder Using Sol-Gel Process (Part 4) Preparation from $ZrOCl_2$ and Colloidal $SiO_2$,' J. Ceram. Soc. Jpn., 99 [3] 227-32 (1991) https://doi.org/10.2109/jcersj.99.227
  25. A. Biswas, 'Preparation and Characterisation of Monolithic Pr-doped Silica,' Mater. Sci. and Eng., 49 [3] 191-96 (1997) https://doi.org/10.1016/S0921-5107(97)00130-X