Phase Changes of Pure Ti During High Temperature Gas Nitriding

순 Ti의 고온 가스질화에 따른 미세조직 변화

  • Lee, H.J. (Forging team, Kisco Corp.) ;
  • Kong, J.H. (Department of Materials Science and Engineering, Dong-A University) ;
  • Bae, J.B. (MIRAE THERMOTEC) ;
  • Seo, J.H. (MIRAE THERMOTEC) ;
  • Kim, Y.H. (Department of Materials Science and Engineering, Dong-A University) ;
  • Sung, J.H. (Department of Materials Science and Engineering, Dong-A University)
  • Published : 2009.03.30

Abstract

The effect of high temperature gas nitrding (HTGN) on the surface microstructure in pure Ti was investigated. Two phases of TiN and $Ti_2N$ appeared at the outmost surface, and the wide ${\alpha}$-Ti layer was formed at the next layer. On the other hand, the interior region, where the nitrogen was not permeated, exhibited ${\alpha}$'phase. The outmost surface of TiN and $Ti_2N$ showed the maximum hardness of 1000Hv, while the interior ${\alpha}$'phase was ${\sim}350$ Hv. The permeation depth of nitrogen increased with increasing the gas nitriding temperature and time. The nitrogen concentration of the surface layer seems to be over 12.7% at $1100^{\circ}C$.

Keywords

References

  1. R. Boyer, G. Welsh, and E. W. Collongs : Materials Properties Handbook Titanuim Alloys, ASM International, Materials Park, OH (1994)
  2. E. W. Collings : The Physical Metallurgy of Titanium Alloys, American Society for Metals (1984)
  3. B. K. Vulf : Electonnoe Materialovedenie, Ti v Electronnoi Tehniki, Energia Press, Moscow (1975)
  4. M. G. Kim and J. K. Gi : Transactions of the KSME A, 221 (1998) 142
  5. D. P. Shashkov, A. V. Vinogradov, and V. N. Polohov : Metals, 6 (1981) 172
  6. H. Shibata, K. Tokaji, T. Ogava, amd C. Hori : Int. J. Fatigue, 16 (1994) 370 https://doi.org/10.1016/0142-1123(94)90448-0
  7. D. P. Shashkov : Metalloved. Term. Obrab. Metall. 6 (2001) 20
  8. G. G. Maksimovich, I. N. Pogreyuk, and V. N. Fedirko : Met. Sci. Heat Treat., 28 (1986) 393 https://doi.org/10.1007/BF00836883
  9. A. Zhecheva, S. Malinov, W. Sha, Z. Metallkd., 94 (2003) 19 https://doi.org/10.3139/146.030019
  10. B. S. Yilbas, A. Z. Sahin, A. Z. Al-Garni, S. A. M. Said, Z. Ahmed, B. J. Abdulaleem, and M. Sami : Surf. Coat. Technol., 80 (1996) 287 https://doi.org/10.1016/0257-8972(95)02472-7
  11. F. Galliano, E. Galvanetto, S. Mischler, and D. Landolt : Surf. Coat. Technol., 145 (2001) 121 https://doi.org/10.1016/S0257-8972(01)01309-3
  12. K. T. Rie : Th. Lampe, St. Eisenberg, Surf. Eng., 1 (1985) 198 https://doi.org/10.1179/sur.1985.1.3.198
  13. J. L. Wayatt, and N. J. Grant : Trans. ASM, 46 (1954) 540
  14. J. L. Wayatt, and N. J. Grant : Iron Age, 14 (1954) 112
  15. K. Bungardt, K. Rudinger, Z. Metallkd., 47 (1956) 577
  16. E. Rolinski, L. Walis, A. Ciurapinski, J. Less-Common Met., 135 (1987) 135 https://doi.org/10.1016/0022-5088(87)90017-8
  17. H. Berns, and S. Siebert : ISIJ International, 36 (1996) 927 https://doi.org/10.2355/isijinternational.36.927
  18. J. H. Sung, J. H. Kong, D. K. Yoo, H. Y. On, D. J. Lee, and H. W. Lee : Materials Science and Engineering A, 489 (2008) 38 https://doi.org/10.1016/j.msea.2007.11.078
  19. 유대경, 공정현, 이해정, 성장현, 이해우 : 대한금속재료학회 46(11) (2008) 708
  20. H. Berns and R. L. Juse : Proceeding the 6th International Seminar of IHFT, yongju, Korea, Oct. 15-18 (1997) 388
  21. H. W. Lee, J. H. Kong, D. J. Lee, H. Y. On, and J. H. Sung : Materials and Design, 30 (2009) 1691 https://doi.org/10.1016/j.matdes.2008.07.023
  22. J. H. Sung, Y. C. Jung, Y. H. Kim, J. H. Sung, and C. Y. Kang : Solid State Phenomena, 118 (2006) 143-148 https://doi.org/10.4028/www.scientific.net/SSP.118.143
  23. D. K. Yoo, H. J. Lee, C. Y. Kang, K. H. Kim, Y. H. Kim, and J. H. Sung : Solid State Phenomena, 118 (2006) 149-154 https://doi.org/10.4028/www.scientific.net/SSP.118.149
  24. H. J. Lee, J. H. Kong, D. K. Yoo, I. S. Kim, and J. H. Sung : ICASS 2006, Kyongju, Korea, Aug. 22-24, (2006) 618-662
  25. Thaddeus B.Massalski, Binary Alloy Phase Diagrams, 2nd Edition, 4 (2000) 2705
  26. S. Malinov, A. Zhecheva, and W. Sha : Proceedings of the 1st International Surface Engineering Congress and 13th IFHTSE Congress, ASM International, Materials Park, OH, (2003) 344