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Effect of elevated temperature on physico-mechanical properties of metakaolin blended cement mortar

  • Morsy, M.S. (Housing & Building National Research Center) ;
  • Rashad, A.M. (Housing & Building National Research Center) ;
  • El-Nouhy, H.A. (Housing & Building National Research Center)
  • Received : 2007.04.19
  • Accepted : 2008.12.04
  • Published : 2009.01.10

Abstract

An experimental investigation was conducted to evaluate the performance of mortars with and without Metakaolin (MK) exposed to elevated temperatures $200^{\circ}C$, $400^{\circ}C$, $600^{\circ}C$ and $800^{\circ}C$ for two hours. The binder to sand ratio was kept constant (1:5.23). The ordinary Portland cement (OPC) was replaced with MK at 0%, 5%, 10% 20% and 30%. All mixtures were designed to have a flow of $94{\pm}5%$. The compressive strength of mortars before and after exposure to elevated temperature was determined. The formation of various decomposition phases were identified using X-ray diffractometry (XRD) and differential thermal analysis (DTA). The microstructure of the mortars was examined using scanning electron microscope (SEM). Test results indicated that MK improves the compressive strength before and after exposure to elevated temperature and that the 20% cement replacement of MK is the optimum percentage.

Keywords

References

  1. Akkan, M.S. and Mazlum, F. (1993), "A comparative study of natural pozzolans used in blended cement production", In: Malhotra, V.M. Editer. Proceedings of the Fourth International Conference on Fly Ash, Silica fume, Slag, and Natural Pozzolans in Concrete, Vol. I. Istanbul, Turkey, May 1992, ACI, 471-494.
  2. Akoz, F., Turker, F. and Semakoral, Yuzer N. (1995), "Effect of sodium sulfate concentration on the sulfate resistance of mortars with and without silica fume", Cement Concrete Res., 6(25), 1360-1368.
  3. Ambroise, J., Maxmilien, S. and Pera, J. (1994), "Properties of metakaolin blended cement", Adv. Cem. Based Mater., 1, 161-168. https://doi.org/10.1016/1065-7355(94)90007-8
  4. Asbrudge, A.H., Jones, T. and Osborne, G.J. (1996), "High performance metakaolin concrete: Results of large scale trials in aggressive environments", In: Dhir, R.K., Hewlett, P.C., editors. Concrete in the Service of Mankinds - Radical Concrete Technology. London E&FN SPON, 13-34.
  5. ASTM C230/C230M-08 Standard Specification for Flow Table for Use in Tests of Hydraulic Cement.
  6. Babu, K.G., Rao, G.S.N. and Prakash, P.V.S. (1993), In: Ravindra K, Dhir, Roderick Jones M, editors. "Efficiency of pozzolans in cement composites", Concrete 2000. Published by E&FNSPON, 497-509.
  7. Badogiannis, E., Papadakis, V.G., Chaniotakis, E. and Tsivilis, S. (2004), "Exploitation of poor greek kaolins: Strength development of metakaolin concrete and evaluation by means of k-value", Cement Concrete Res., 34, 1035-1041. https://doi.org/10.1016/j.cemconres.2003.11.014
  8. Badogiannis, E., Tsivilis, S., Papadakis, V. and Chaniotakis, E. (2002), "The effect of metakaolin on concrete properties", In: Dhir, R.K., Hewlett, P.C., Cetenyi, L.J., editors. Innovations and Developments in Concrete Materials and Construction. UK: Dundee, 81-89.
  9. Basheer, P.A.M., McCabe, C.C. and Long, A.E. (1999), "The influence of metakaolin on properties of fresh and hardened concrete", In: Swamy RN, editor. Proceedings of the International Conference on Infrastructure Regeneration and Rehabilitation Improving the Quality of Life Through Better Construction, 199-211.
  10. Batis, G., Pantazopoulou, P., Tsivilis, S. and Badogiannis, E. (2002), "Corrosion resistance of cement mortars with metakaolinite", In: Dhir, R.K., Hewlett, P.C., Cetenyi, L.J., editors. Innovations and Developments in Concrete Materials and Construction. UK: Dundee, 357-366.
  11. Brooks, J.J., Megat Johari, M.A. and Mazloom, M. (2000), "Effect of admixtures on the setting times of high strength concrete", Cement Concrete Compos., 22, 293-301. https://doi.org/10.1016/S0958-9465(00)00025-1
  12. Cook, D.J. (1985), "Calcined clay, shale and other soils", Cement. Cement Replacement Materials - Concrete Technology and Design, Vol. 3. Surrey University Press, 40-70.
  13. De Silva, P.S. and Glasser, F.P. (1990), "Hydration of cements based on metakaolin: Thermochemistry", Adv Cement Res., 3, 167-177. https://doi.org/10.1680/adcr.1990.3.12.167
  14. Dunster, A.M., Parsonage, J.R. and Thomas, M.J.K. (1993), "Pozzolanic reaction of metakaolinite and its effects on Portland cement hydration", J. Mater. Sci., 28, 1345-1351. https://doi.org/10.1007/BF01191976
  15. Gallias, J.L., Kara-Ali, R. and Bigas, J.P. (2000), "The effect of fine mineral admixtures on water requirement of cement pastes", Cement Concrete Res., 30, 1543-1549. https://doi.org/10.1016/S0008-8846(00)00380-X
  16. Xu, G.J.Z., Watt, D.F. and Hudec, P.P. (1995), "Effectiveness of mineral admixtures in reducing ASK expansion", Cement Concrete Res., 6(25), 1225-1235.
  17. Gruber, K.A., Ramlochan, T., Boddy, A., Hooton, R.D. and Thomas, M.D.A. (2001), "Increasing concrete durability with high-reactivity metakaolin", Cement Concrete Compos., 23, 479-484. https://doi.org/10.1016/S0958-9465(00)00097-4
  18. Guneyisi, E. and Mermerdas, K. (2007), "Comparative study on strength, sorptivity, and chloride ingress characteristics of air-cured and water-cured concretes modified with metakaolin", Mater. Struct., 40, 1161-1171. https://doi.org/10.1617/s11527-007-9258-5
  19. He, C., Makavicky, E. and Osback, B. (1994), "Thermal stability and pozzolanic activity of calcined kaolin", Appl Clay Sci., 9, 165-187. https://doi.org/10.1016/0169-1317(94)90018-3
  20. Kakali, G., Perraki, T., Tsivilis, S. and Badogiannis E. (2001), "Thermal treatment of kaolin: The effect of mineralogy on the pozzolanic activity", Appl. Clay Sci., 20, 73-80. https://doi.org/10.1016/S0169-1317(01)00040-0
  21. Kaloumenou, M., Badogiannis, E., Tsivilis, S. and Kakali, G. (1999), "Effect of the kaolin particle size on the pozzolanic behavior of the metakaolinite produced", J. Therm. Anal. Calorim., 56, 901-907. https://doi.org/10.1023/A:1010143214686
  22. Kostuch, J.A., Walter, G.V. and Jones, T.R. (2000), "High performance concretes containing metakaolin", - A review. In: Proceedings of the International Conference - Concrete 2000, Dundee, 2, 1799-1811.
  23. Kostuch, J.A., Walters, V. and Jones, T.R. (1996), "High performance concretes incorporating metakaolin: A review", In: Dhir, R.K., Jones, M.R., editors. Concrete 2000: Economic and Durable Construction Through Excellence. London: E&FN SPON, 1799-1811.
  24. Kristof, E., Juhasz, A.Z. and Vassanyi, I. (1993), "The effect of mechanical treatment on the crystal structure and thermal behavior of kaolinite", Clays Clay Miner., 41, 608-612. https://doi.org/10.1346/CCMN.1993.0410511
  25. Lin, W.M., Lin, T.D. and Powers-Couche, L.J. (1996), "Microstructures of fire damaged concrete", ACI Mater. J., 93(3), 199-205.
  26. Moulin, E., Blanc, P. and Sorrentino, D. (2001), "Influence of key cement chemical parameters on the properties of metakaolin blended cements", Cement Concrete Compos., 23, 463-469. https://doi.org/10.1016/S0958-9465(00)00093-7
  27. Nimityongskul, P. and Daladar, T.U. (1995), "Use of coconut husk ash, corn cob ash and peanut shell ash as cement replacement", J. Ferrocement, 25(1), 35-44.
  28. Oriel, M. and Pera, J. (1995), "Pozzolanic activity of metakaolin under microwave treatment", Cement Concrete Res., 25(2), 265-270. https://doi.org/10.1016/0008-8846(95)00007-0
  29. Palomo, A., Blanco-Varela, M.T., Granizo, M.L., Puertas, F., Vazquez, T. and Grutezeck, M.W. (1999), "Chemical stability of cementitious materials based on metakaolin", Cement Concrete Res., 29, 997-1004. https://doi.org/10.1016/S0008-8846(99)00074-5
  30. Phan L.T. (1996), "Fire performance of high strength concrete", A Report of the State-of-the-art. Maryland: Building and Fire Research Laboratory, National Institute of Standards and Technology.
  31. Poon Chi-Sun, Azhar Salama, Anson Mike and Wong Yuk-Lung (2003), "Performance of metakaolin concrete at elevated temperature", Cement Concrete Compos., 25, 83-89. https://doi.org/10.1016/S0958-9465(01)00061-0
  32. Ramlochan, T., Thomas, M. and Gruber, K.A. (2000), "The effect of metakaolin on alkali-silica reaction in concrete", Cement Concrete Res., 30, 339-344. https://doi.org/10.1016/S0008-8846(99)00261-6
  33. Ruiz, A.L. (1965), "Strength contribution of a pozzolan to concretes", Proc. J. Amer. Conc. Inst., 62, 315-324.
  34. Sabir, B.B., Wild, S. and Bai, J. (2001), "Metakaolin and calcined clays as pozzolans for concrete: A review", Cement Concrete Compos., 23, 441-454. https://doi.org/10.1016/S0958-9465(00)00092-5
  35. Sha, W. and Pereira, B. (2001), "Differential scanning calorimetry study of ordinary Portland cement paste containing metakaolin and theoretical approach of metakaolin activity", Cement Concrete Compos., 23, 455-461. https://doi.org/10.1016/S0958-9465(00)00090-1
  36. Shvarzman, A., Kovler, K., Schamban, I., Grader, G.S. and Shter, G.E. (2002), "Influence of chemical and phase composition of mineral admixtures on their pozzolanic activity", Adv. Cement Res., 14(1), 35-41. https://doi.org/10.1680/adcr.2002.14.1.35
  37. Vu, D.D. (1996), "The effect of kaolin on characteristics of blended Portland cement paste and mortar", Report 03.21.1.32.05, Faculty of Civil Engineering. Delft University of Technology, Delft.
  38. Vu, D.D. (1996), "The effect of kolin on characteristics of blended Portland cement paste and mortar", Report 03.21.1.32.30, Faculty of Civil Engineering. Delft University of Technology, Delft.
  39. Vu, D.D., Stroeven, P. and Bui, V.B. (2001), "Strength and durability aspects of calcined kaolin-blended Portland cement mortar and concrete", Cement Concrete Compos., 23, 471-478. https://doi.org/10.1016/S0958-9465(00)00091-3
  40. West, J., Atkinson, C. and Howard, N. (1994), "Embodied energy and carbon dioxide emissions for building materials", In: Proceedings of the 1st International Conference on Buildings and the Environment, CIB Task Group 8. Environmental Assessment of Buildings, BRE Watford, UK, 16-20 May.
  41. Wild, S., Khatib, J.M. and Jones, A. (1996), "Relative strength pozzolanic activity and cement hydration in superplasticised metakaolin concrete", Cement Concrete Res., 26, 1537-1544. https://doi.org/10.1016/0008-8846(96)00148-2

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