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SrTiO3 치환에 따른 (Na,K)NbO3계 세라믹스의 유전 및 압전특성

Dielectric and Piezoelectric Properties of (Na,K)$NbO3 Ceramics as a Function of SrTiO3 Substitution

  • 발행 : 2009.06.01

초록

In this study, in order to develop the lead-free piezoelectric ceramics with high piezoelectric and dielectric properties, $[(K_{0.5}Na_{0.5})_{0.95}Li_{0.05}(Nb_{0.96}Sb_{0.04})]O_3$ ceramics were fabricated using $Ag_2O$ as sintering aid and a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $SrTiO_3$ substitution. $SrTiO_3$ substitution enhanced density, dielectric constant(${\varepsilon}_r$) and electromechanical coupling factor($k_p$). However, mechanical quality factor was deteriorated. And also, Curie temperature ($T_c$), and phase transition temperature($T_p$) were rapidly decreased. At the 0.5 mol% $SrTiO_3$ substitution, density, electromechanical coupling factor($k_p$), dielectric constant(${\varepsilon}_r$) and piezoelectric constant($d_{33}$) of specimen showed the optimum value of $4.437\;g/cm^3$, 0.457, 1294, 265 pC/N, respectively.

키워드

참고문헌

  1. Y. H. Jeong, J. H. Yoo, S. H. Lee, and J. I. Hong, 'Piezoelectric characteristics of low temperature sintering $Pb(Mn_{1/3}Nb_{2/3})O_3-Pb(Ni_{1/3}Nb_{2/3})O_3-Pb(Zr_{0.50}Ti_{0.50})O_3$ according to the addition of CuO and $Fe_2O_3$', Sensors and Actuators A, Vol. 135, No. 1, p. 215, 2007 https://doi.org/10.1016/j.sna.2006.06.073
  2. S. H. Lee, J. H. Yoo, I. S. Kim, and J. S. Song, 'Piezoelectric characteristics of low temperature sintering $Pb(Ni_{1/3}Nb_{2/3})O_3-Pb(Zr_{1/2}Ti_{1/2})O_3$ ceramics as a function of $Pb(Mn_{1/3}Sb_{2/3})O_3$ substitution', Jouranl of Electroceramics, Online https://doi.org/10.1007/s10832-008-9482-6
  3. Y. Wang, J. Wu, D. Xiao, J. Zhu, P. Yu, L. Wu, and X. Li, 'Piezoelectric properties of (Li, Ag, Sb) modified $(K_{0.50}Na_{0.50})NbO_3$ lead- free ceramics', J. Alloys Comp., Vol. 462, p. 310, 2008 https://doi.org/10.1016/j.jallcom.2007.08.034
  4. 이갑수, 류주현, 홍재일, 이석태, 김용운, 정회승, 'Na/K 비 변화에 따른 무연 $[Li_{0.04}(Na_yK_{1-y})_{0.94}](Nb_{0.86}Ta_{0.2}Sb_{0.04})O_3$ 세라믹스의 압전 및 유전특성', 전기전자재료학회논문지, 20권, 1호, p. 25, 2007 https://doi.org/10.4313/JKEM.2007.20.1.025
  5. R. Wang, R. Xie, K. Hanada, K. Matsusak, H. Bando, and M. Itoh, 'Phase diagram and enhanced piezoelectricity in the strontium titanate doped potassium–sodium niobate solid solution', Phys. Stat. Sol., Vol. 202, No. 6, p. R57, 2005 https://doi.org/10.1002/pssa.200510014
  6. M. Kosec, V. Bobnar, M. Hrovat, J. Bernard, B. Malic, and J. Holc, 'New lead-free relaxor. based on the $K_{0.5}Na_{0.5}NbO_3-SrTiO_3$ solid solution', J. Mater. Res., Vol. 19, No. 6, p. 1849, 2004 https://doi.org/10.1557/JMR.2004.0229
  7. Y. Guo, K. Kakimoto, and H. Ohsato, 'Dielectric and piezoelectric properties of lead-free$(Na_{0.5}K_{0.5})NbO_3-SrTiO_3$ ceramics', Sol. Stat. Comm., Vol. 129, p. 279, 2004 https://doi.org/10.1016/j.ssc.2003.10.026

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