Journal of the Mineralogical Society of Korea (한국광물학회지)

The Mineralogical Society of Korea (한국광물학회)
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Phosphate Desorption of Kaolinite KGa-1b (Source Clay)

카올리나이트 KGa-1b (표준 점토)의 인산염 탈착 특성

  • Cho, Hyen-Goo (Department of Earth and Environmental Sciences and Research Institute of Natural Science, Gyeongsang National University) ;
  • Kim, Soo-Oh (Department of Earth and Environmental Sciences and Research Institute of Natural Science, Gyeongsang National University) ;
  • Choo, Chang-Oh (Department of Earth and Environmental Sciences, Andong National University) ;
  • Do, Jin-Young (School of Cultural Assets, Gyeongju University)
  • 조현구 (경상대학교 지구환경과학과 및 기초과학연구소) ;
  • 김순오 (경상대학교 지구환경과학과 및 기초과학연구소) ;
  • 추창오 (안동대학교 지구환경과학과) ;
  • 도진영 (경주대학교 문화재학부)
  • Published : 2009.12.30
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Abstract

The characteristics of phosphate desorption on kaolinite was studied by batch adsorptiondesorption experiments. Desorption procedure was carried out through sequential extraction method at pH 4. The phosphorous contents were measured using UV-VIS-IR spectrophotometer with 820 nm wavelength. The adsorption-desorption reaction of P on kaolinite was irreversible, and most of adsorbed P on kaolinite were not easily dissolved to aqueous solution, but may might be fixed on kaolinite surface. The desorption isotherms were well fitted with the Freundlich and Temkin equations in the case of short reaction and long reaction time, respectively. The desorption reaction was divided into the early fast reaction and the later slow reaction. The percentage of desorption generally decreased with increasing adsorbed P concentration and increasing desorption reaction time.

카올리나이트 KGa-1b (표준 점토)의 인산염 탈착 특성을 규명하기 위하여 벳치(batch) 흡착-탈착 실험을 실시하였으며, 탈착 과정은 연속추출법에 따라 pH 4에서 시행하였다. 인의 함량은 UV 분광분석기를 시용하여 측정하였으며, 이 때 파장은 820 nm를 이용하였다. 카올리나이트의 인산염 흡착-탈착 반응은 비가역적으로 일어나며, 흡착된 대부분의 인산염은 고착되는 경향을 나타낸다. 인산염 탈착 등온선은 반응 시간이 짧은 경우 프로인드리히 등온선에, 반응 시간이 긴 경우 탬킨 등온선에 더 일치하는 경향을 보인다. 인산염 탈착 반응은 초기의 빠른 반응과, 후기의 느린 반응으로 구분된다. 흡착된 인산염의 농도가 높아질수록 탈착률은 감소하는 경향을 보이며, 탈착 시간이 길어지면 탈착률은 감소하는 경향을 보여준다.

Keywords

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